无机温芯盒粘结剂与原砂适配性能及其界面附着机理OA
Adaptability and Interface Adhesion Mechanism of Inorganic Warm Core Box Binder with Base Sand
无机粘结剂技术是环境友好型铸造材料的重要发展方向之一,近三十年来在铸铝、铸铁及铸钢领域不断取得突破.本研究以圣泉集团SQ无机粘结剂为对象,系统比较了该粘结剂在不同细度的宝珠砂与硅砂两种原砂中的性能差异,并对原砂进行了粒度、光学显微镜、电导率、角形因数、比表面积和扫描电镜等表征.结果表明,原砂类型显著影响粘结剂性能.在低粘结剂用量下,宝珠砂试样的即时抗弯强度和1 h抗弯强度显著优于硅砂试样,甚至优于硅砂试样在高粘结剂用量时的强度,这主要归因于宝珠砂特殊的表面结构所带来的强附着强度.通过SEM表征还发现,原砂表面粘结剂膜厚存在差异,宝珠砂表面粘结剂膜厚的实测值显著低于理论计算值,而硅砂的实测值略低于计算值,这一发现进一步证明了原砂表面结构对粘结剂强度性能的正面影响.本研究揭示了原砂特性对无机粘结剂性能的影响,为深入理解无机粘结剂与原砂的界面作用机制,优化造型工艺条件,拓展宝珠砂在铸铝领域的应用提供了依据和数据支撑.
The inorganic binder technology is one of important developing directions of environmentally friendly foundry materials,which has been achieved breakthroughs continuously in aluminum,iron,and steel casting fields for recent thirty years.In this investigation,taking the SQ inorganic binder of Shengquan Group as object,the differences of the binder performances were systimatically compared in two kinds of base sands of ceramite sand and silica sand with different fineness levels,and the characterizations of particle size,optical microscope,electrical conductivity,angularity factor,specific surface area,SEM,and so on were carried out for the base sands.The results demonstrate that the base sand type obviously affects the binder performance.Under the condition of a low binder addition,the initial flexural strengths and 1-hour flexural strengths of the ceramite sand samples are obviously higher that of the silica sand samples,even higher than that of the silica sand samples under the condition of a high binder addition,and this is primarily attributed to the strong adhesive strength resulted from the unique surface structure of the ceramite sand.It is also found through SEM characterization that the binder film thicknesses on the surfaces of base sands exist difference.The measured values of the binder film thicknesses on the surfaces of ceramite sands are much lower than the theoretical calculation values,while the measured values for silica sands are a little more than the calculation values,and this discovery further verified the positive effect of the base sand surface structure on the strengh property of binder.This investigation revealed the influence of base sand characteristics on the binder performances,and provided basis and essential data for in-depth understanding of the interfacial interaction mechanism between the inorganic binder and base sand,optimizing the molding process conditions,and expanding the application of ceramite sand in aluminum casting field.
王长旭;刘烨;袁永;杨宗锋;张杨;周国栋;刘伟伟;马丽;张用吉;张丽娟
济南圣泉集团股份有限公司,山东 济南 250204济南圣泉集团股份有限公司,山东 济南 250204济南圣泉集团股份有限公司,山东 济南 250204济南圣泉集团股份有限公司,山东 济南 250204济南圣泉集团股份有限公司,山东 济南 250204济南圣泉集团股份有限公司,山东 济南 250204济南圣泉集团股份有限公司,山东 济南 250204济南圣泉集团股份有限公司,山东 济南 250204济南圣泉集团股份有限公司,山东 济南 250204济南圣泉集团股份有限公司,山东 济南 250204
矿业与冶金
无机粘结剂原砂宝珠砂硅砂抗弯强度界面作用表面结构温芯盒法
inorganic binderbase sandceramite sandsilica sandflexural strengthinterface interactionsurface structurewarm-box process
《铸造》 2026 (4)
352-360,9
圣泉技术创新项目(2024637010000935).
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