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复合抑尘剂强化润湿作用机理及应用效果研究OA

Study on the enhancing wetting mechanism and application effect of compound dust suppressants

中文摘要英文摘要

为提高低渗煤层注水润湿的抑尘效果,通过煤样沉降试验、接触角测试及酸蚀率测试,优选出由"表面活性剂+无机盐助剂+酸蚀剂"组成的复合抑尘剂:质量分数 0.8%的十二烷基硫酸钠(SDS)、质量分数 0.2%的椰油酸二乙醇胺、质量分数 0.8%的氯化钠(NaCl)、质量分数4.0%的盐酸(HCl).借助红外光谱试验与冲击产尘试验,分析了复合抑尘剂对煤体官能团变化及破碎产尘特性的影响.结合已有研究成果和现场条件,构建了"动静压注水+复合抑尘剂"的物化协同注液润湿抑尘系统,并在杜儿坪矿进行了应用测试.结果表明:复合抑尘剂可使煤样接触角较清水降低 50%以上,沉降时间缩短至 47 s,煤体溶蚀率达到 3.26%.复合抑尘剂能显著改变煤体中芳香烃、含氧官能团、脂肪烃及烃基等组分的结构,使煤体结构更为疏松,进而促进水分渗透,同时调节煤体表面电荷分布,增强对水分子的吸附能力,全面提升煤体润湿性能.经复合抑尘剂处理后的煤样在破碎过程中粉尘更易团聚为大颗粒脱落,粒径 74 μm以下的粉尘质量分数相较于清水润湿煤样下降 54%.复合抑尘剂分子可渗入煤体内部微孔隙,改变其表面物理化学性质,增强内部结合力,从而抑制破碎过程中细小颗粒的扩散.应用物化协同注液润湿抑尘技术后,现场煤层单孔注水量较静压注水提高 1.37 倍,含水率增量提升 1.4 倍,湿润半径扩大 50%,回采工作面粉尘质量分数下降 50%以上,作业环境显著改善.

In order to improve the effect of low-permeability coal bed water injection wetting and dust suppression,the compound dust suppressant material of"surfactant+inorganic salt additives+acid corrosive agent"was selected through the experiments of settlement of coal samples,contact angle test and acid etching rate test.The optimal mass fractions are 0.8%sodium dodecyl sulfate(SDS),0.2%coconut oil fatty acid diethanolamide,0.8%sodium chloride(NaCl),and 4.0%hydrochloric acid(HCl).The infrared spectroscopy experiment and impact dust production experiment were carried out to clarify the changes of coal functional groups and the characteristics of broken dust production under the effect of compound dust suppressant.Based on the existing research and field layout,the physical and chemical synergistic liquid wetting and dust suppression system of"dynamic and static pressure water injec-tion+compound dust suppressant"was constructed and applied in Duerping Mine.The results show that the compound dust sup-pressant can reduce the contact angle of coal samples by more than 50%compared with that of clear water,the settling time is only 47 s,and the dissolution rate of coal body reaches 3.26%.The dust suppressant can significantly change the structures of aromatic hydrocarbons,oxygen-containing functional groups,aliphatic hydrocarbon and hydrocarbon groups in coal,making the structure of the coal body more loose and thus promoting the penetration of water,and adjusting the distribution of the charge on the surface of the coal body at the same time,enhancing the attraction to water molecules,and all-roundedly enhancing the wetting performance of the coal body.After the action of compound dust suppressant,the coal samples are easier to combine the dust during crushing,and fall off in the form of dust with large particle size,and the percentage of dust below 74 μm drops by 54%compared with that of coal samples wetted with water.The molecules of the compound dust suppressant are able to penetrate into the tiny pores inside the coal body,change the physicochemical properties of the surface of the coal body,enhance the combining force inside the coal body,and inhibit the dispersion of small particles during the process of crushing.After adopting the physical and chemical synergistic liquid in-jection wetting and dust suppression technology,the amount of water injected into the single hole of the coal seam at the site in-creased by 1.37 times compared with the hydrostatic injection,the incremental water content was improved by 1.4 times,the wetting radius was enlarged by 50%,and the concentration of dust during the back-mining was reduced by more than 50%,so that the operat-ing environment of the site was significantly improved.

王晓斌;胡胜勇;孙修伟;原振淇;胡泊;贾国彪

太原理工大学 安全与应急管理工程学院,山西 太原 030024太原理工大学 安全与应急管理工程学院,山西 太原 030024太原理工大学 安全与应急管理工程学院,山西 太原 030024太原理工大学 安全与应急管理工程学院,山西 太原 030024太原理工大学 安全与应急管理工程学院,山西 太原 030024太原理工大学 安全与应急管理工程学院,山西 太原 030024

矿业与冶金

煤层注水低渗煤层润湿抑尘复合抑尘剂脉动注水

coal seam water injectionlow-permeability coal seamwetting and dust suppressioncompound dust suppressantpulsating water injection

《煤矿安全》 2026 (3)

18-30,13

"十四五"国家重点研发计划政府间重点专项资助项目(2023YFE0103400)山西省科技重大专项计划"揭榜挂帅"资助项目(202301080301005)

10.13347/j.cnki.mkaq.20250302

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