脱气处理对XLPE材料直流电树枝引发及生长的影响规律OA
The influence of degassing treatment on the initiation and growth of DC electrical treeing in XLPE material
交联聚乙烯(cross-linked polyethylene,XLPE)电缆在制造过程中产生的交联副产物,如苯乙酮、枯基醇和 α-甲基苯乙烯,会在电场作用下解离形成空间电荷,导致电树枝的引发和生长,进而降低电缆的绝缘性能.脱气处理是减少交联副产物的有效方法之一,然而脱气时间的选择目前主要依赖经验,缺乏统一标准.文中采用气相色谱-质谱法定量分析交联副产物的体积分数变化与脱气时间的关系,并结合电树枝引发和生长实验,研究交联副产物在直流电树枝生长过程中的作用机理.实验结果表明,脱气处理对降低 3种交联副产物的体积分数有明显效果,其中α-甲基苯乙烯脱出效果最明显.在不同脱气阶段,交联副产物的体积分数下降速率各不相同,并且交联副产物体积分数的下降使得电树枝的引发与生长更加困难,在实际工业生产中,脱气应保证交联副产物的体积分数下降至初始体积分数的 20%以下.文中研究为优化 XLPE电缆的脱气工艺提供了理论依据,在实际生产中采用合理的脱气时间,可以最大限度地减少交联副产物,提升电缆的绝缘性能和使用寿命.
Cross-linked polyethylene(XLPE)cables generate cross-linking by-products such as acetophenone,cumyl alcohol,and α-methylstyrene during the manufacturing process.Under the influence of an electric field,these by-products dissociate,forming space charges that lead to the initiation and growth of electrical treeing,thereby reducing the insulation performance of the cables.Degassing treatment is considered one of the effective methods for reducing cross-linking by-products.However,the current selection of degassing time mainly relies on experience and lacks a unified standard.The effect of degassing time on the initiation and growth characteristics of electrical treeing in XLPE cables is experimentally investigated.Gas chromatography-mass spectrometry(GC-MS)is used to quantitatively analyze the changes in the volume fraction of cross-linking by-products.In conjunction with electrical treeing initiation and growth experiments,the mechanism by which cross-linking by-products influence the growth of DC electrical treeing is explored.The experimental results show that degassing treatment has a significant effect on reducing the volume fraction of all three cross-linking by-products,with α-methylstyrene exhibiting the most pronounced removal.The rate of decline in cross-linking by-product volume fraction varies at different stages of degassing.The reduction in cross-linking by-products makes the initiation and growth of electrical treeing more difficult.In practical industrial production,degassing should ensure that the volume fraction of cross-linking by-products is reduced to less than 20%of the initial level.A theoretical basis is provided for optimizing the degassing process of XLPE cables,and a reasonable degassing time is recommended for use in actual production to minimize cross-linking by-products,thereby enhancing the insulation performance and service life of the cables.
李柏雨;郑喆;张洪亮;赵谡;赵孝磊;尹毅
上海交通大学电子信息与电气工程学院,上海 201100上海交通大学电子信息与电气工程学院,上海 201100上海交通大学电子信息与电气工程学院,上海 201100||中天科技海缆股份有限公司,江苏 南通 226010上海交通大学电子信息与电气工程学院,上海 201100上海交通大学电子信息与电气工程学院,上海 201100上海交通大学电子信息与电气工程学院,上海 201100
信息技术与安全科学
交联聚乙烯(XLPE)高压直流电缆脱气处理电树枝交联副产物空间电荷
cross-linked polyethylene(XLPE)high voltage direct current cabledegassing treatmentelectrical treeingcross-linking by-productsspace charge
《电力工程技术》 2026 (4)
94-100,7
国家自然科学基金资助项目(52107019)
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