首页|期刊导航|安全、健康和环境|多组分可燃气体爆炸极限预测研究进展

多组分可燃气体爆炸极限预测研究进展OA

Research Progress on Flammability Limit Prediction of Multi-Component Combustible Gases

中文摘要英文摘要

爆炸极限是评估可燃气体燃爆危险性的关键参数之一,其在化工、能源、采矿等工业安全领域具有重要基础地位.为实现对可燃气体燃爆事故的有效防控,系统梳理了单组分及多组分可燃气体体系爆炸极限的预测方法.重点剖析了化学计量浓度法、燃烧热估算法、Larry 公式、Le Chatelier 公式及绝热火焰温度法等经典理论模型,对比分析了其适用范围与预测偏差,并探讨了适用于高温、高压等苛刻条件下的预测模型.研究结果表明:经典理论模型在预测常温常压条件下烃类物质的爆炸下限时准确度较高;然而,在高温高压条件下,现有预测模型多为基于实验数据拟合的经验或半经验关联式,普遍存在预测精度不足、泛化能力弱的问题.基于此,未来研究应致力于发展多物理场、多尺度耦合的先进模型,大力创新人工智能驱动的智能预测方法,并重点突破新能源体系的安全评估关键技术,从而不断完善燃爆理论体系,为工业安全防护水平的实质性提升提供支撑.

The flammability limit is a key parameter for assessing the combustion and explosion hazards of flammable gases,holding fundamental importance in industrial safety sectors such as chemical engineering,en-ergy,and mining.To enable effective prevention and control of flammable gas accidents,this paper systemati-cally reviewed prediction methods for the flammability limits of both single-component and multi-component mix-tures.It focused on analyzing classical theoretical models-including the heat of combustion method,stoichiomet-ric concentration method,Larry's formula,Le Chatelier's formula,and adiabatic flame temperature method.This study compared their applicable ranges and prediction deviations,and discussed models suited for harsh conditions such as high temperatures and high pressures.The results indicated that classical theoretical models achieved high accuracy in predicting the lower flammability limits of hydrocarbons under normal temperature and pressure.However,under high-temperature and high-pressure conditions,existing prediction models were pri-marily empirical or semi-empirical correlations derived from experimental data,which generally suffered from in-sufficient prediction accuracy and weak generalization capability.Based on these findings,future research should aim to develop advanced models incorporating multi-physics and multi-scale coupling,vigorously promote innovation in artificial intelligence-driven intelligent prediction methods,and achieve key breakthroughs in safe-ty assessment technologies for emerging energy systems.These efforts will contribute to refining the theory of combustion and explosion and provide substantial support for enhancing industrial safety protection levels.

盛晓

化学品安全全国重点实验室,山东 青岛 266104||中石化安全工程研究院有限公司,山东 青岛 266104

资源环境

爆炸极限预测方法可燃气体多组分混合气体高温高压

flammability limitsprediction methodsflammable gasesmulticomponent mixtureshigh-temperature and high-pressure

《安全、健康和环境》 2026 (3)

1-11,11

中国石化科技部项目(KL324005),过氧化工艺本质安全化关键模型方法和支撑系统研究.

10.3969/j.issn.1672-7932.2026.03.001

评论