煤粉炉掺烧芦竹NOx生成特性模拟研究OA
Simulation study on nitrogen oxides formation characteristics during co-combustion with arundo donax in a pulverized-coal boiler
燃煤耦合生物质发电是燃煤机组有效降碳的技术之一,芦竹作为典型的能源植物具有产量高、环境适应性强、热值高等特点,可以大规模用于燃煤机组发电.为研究煤粉炉在燃煤过程中掺烧芦竹对NOx排放的影响,探究煤和芦竹混燃过程中燃料氮的迁移路径,利用两段PFR构建了芦竹与煤混燃反应模型,研究了煤粉炉掺烧芦竹NOx生成特性与反应机理,重点探讨了掺混比例、燃尽风率和燃尽风位置等因素对NOx生成特性的影响规律.结果表明:掺烧芦竹可以降低NOx排放,且随着掺混比例的增加,NOx的质量浓度逐渐减小;随着燃尽风率的增加,NOx的转化率和NOx的质量浓度先减小后增大,存在一个最佳燃尽风率(33%)使NOx排放量最低;随着燃尽风位置的后置,NOx转化率和NOx质量浓度都减小.通过研究煤和芦竹混燃过程中NOx生成特性及氮的迁移路径,为燃煤机组掺烧芦竹发电过程中的参数设置和降低尾气NOx排放提供理论指导.
Coal-fired power generation coupled with biomass is one of the efficient carbon-reduction technologies for coal-fired units.As a typical energy plant,arundo donax has the characteristics of high yield,strong environmental adaptability and high calorific value,and can be used for large-scale coal-fired power generation.To investigate the effect of co-firing arundo donax in a pulverized-coal boiler on NOx emissions and explore the migration pathways of fuel nitrogen during the co-combustion of coal and arundo donax,a co-combustion reaction model of arundo donax and coal was established with a two-stage plug flow reactor(PFR).The formation characteristics and reaction mechanisms of nitrogen oxides during co-combustion of the arundo donax and coal in a pulverized-coal boiler were studied,focusing on exploring the influences of co-firing ratio,over-fire air(OFA)ratio,and OFA position on the formation characteristics of nitrogen oxides.The results show that the NOx emission can be reduced by co-firing arundo donax,and the mass concentration of NOx decreases with the increase in co-firing ratio of arundo donax.The NOx conversion rate and NOx mass concentration first decrease and then increase with the increase in over-fire air ratio,and there is an optimal over-fire air ratio(around 33%)to minimize NOx emissions.Delaying the position of the OFA leads to a decrease in both the NOx conversion rate and NOx mass concentration.By studying the NOx formation characteristics and the nitrogen migration pathways during co-combustion of coal and arundo donax,theoretical guidance can be provided for parameter setting and reducing exhaust NOx emissions in the co-combustion of arundo donax for coal-fired power generation.
刘凌;陈祺;郝建材;陆利俊;许香婷;王长安;柳明;杜勇博;车得福
上海上电漕泾发电有限公司,上海 201507上海上电漕泾发电有限公司,上海 201507西安交通大学绿色氢电全国重点实验室,陕西 西安 710049上海上电漕泾发电有限公司,上海 201507西安交通大学绿色氢电全国重点实验室,陕西 西安 710049西安交通大学绿色氢电全国重点实验室,陕西 西安 710049上海发电设备成套设计研究院有限责任公司,上海 200240西安交通大学绿色氢电全国重点实验室,陕西 西安 710049西安交通大学绿色氢电全国重点实验室,陕西 西安 710049
芦竹混燃煤粉炉氮氧化物化学反应动力学模拟
arundo donaxco-combustionpulverized-coal boilernitrogen oxideschemical reactionkinetic simulation
《热力发电》 2026 (3)
100-109,10
陕西省重点研发项目(2024GX-YBXM-478) Key Research and Development Project of Shaanxi Province(2024GX-YBXM-478)
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