磷酸酯抗燃油成分分析及性能研究OA
Composition analysis and properties of phosphate ester fire-resistant fluid
磷酸酯抗燃油作为电厂汽轮机调速系统的工作介质,对汽轮机的正常运转起着至关重要的作用.运行中因油质劣化可能出现油质酸值升高,体积电阻率下降,以及生成油泥的情况,不同油品分解劣化程度不一致.对不同种类磷酸酯抗燃油化学成分进行分析,模拟不同磷酸酯分子劣化过程,并检测其抗老化性能.结果表明:以三-(二甲基苯基)磷酸酯为主要组分的磷酸酯抗燃油稳定性能优于以叔丁基苯基磷酸酯为主要组分的磷酸酯抗燃油;在研制磷酸酯抗燃油过程中,应提高三芳基磷酸酯中二甲基苯基的含量,降低苯基和叔丁基苯基的含量.
As the working medium of turbine speed-control systems in power plants,phosphate ester fire-resistant fluid(FRF)plays a vital role in the normal operation of steam turbines.During operation,the deterioration of FRF may result in an increase in acid value,a decrease in volume resistivity,and the formation of oil sludge,and the degree of decomposition and deterioration varies among different oils.The chemical composition of different kinds of FRF samples was analyzed,the deterioration process of different phosphate ester molecules was simulated,and their aging-resistance properties were tested.The results show that the performance of FRF with tris-(dimethylphenyl)phosphate as the main component is more stable than that of FRF with tert-butylphenyl phosphate as the main component.During the production of FRF,the content of dimethylphenyl in triaryl phosphate should be increased,and the content of phenyl and tert-butyl phenyl should be reduced.
高占阳;韩明睿;刘杰;王笑微;张帆;王娟;崔锐;龙国军;王宇;徐勇智;王伦
西安热工研究院有限公司,陕西 西安 710054华能甘肃能源开发有限公司西固分公司,甘肃 兰州 730070华能甘肃能源开发有限公司西固分公司,甘肃 兰州 730070西安热工研究院有限公司,陕西 西安 710054华能甘肃能源开发有限公司西固分公司,甘肃 兰州 730070西安热工研究院有限公司,陕西 西安 710054华能甘肃能源开发有限公司西固分公司,甘肃 兰州 730070西安热工研究院有限公司,陕西 西安 710054西安热工研究院有限公司,陕西 西安 710054华能甘肃能源开发有限公司西固分公司,甘肃 兰州 730070西安热工研究院有限公司,陕西 西安 710054
磷酸酯抗燃油化学成分芳基酚抗老化性能
phosphate ester fire-resistant fluidchemical compositionaryl phenolaging resistance performance
《热力发电》 2026 (3)
64-71,8
中国华能集团有限公司总部科技项目(HNKJ23-H22) Science and Technology Project of China Huaneng Group Co.,Ltd.(HNKJ23-H22)
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