化学淋洗法修复盐渍化Pb污染土壤OA
Remediation of Lead Pollution in Salinized Soil Using Chemical Leaching
以宁夏典型农灌区镇河村农田土壤为研究对象,采用批量实验,结合土柱实验方法,研究淋洗剂种类、浓度、用量及淋洗时间对模拟Pb污染土壤中Pb去除率的影响;采用土柱模拟实验方法,研究淋洗法修复不同Pb质量比和不同程度盐渍化Pb污染土壤.结果表明,乙二胺四乙酸二钠(EDTA-2Na)溶液对盐渍化土壤中Pb的去除率最高,且在1 g土壤中EDTA-2Na溶液的用量为10 mL、c(EDTA-2Na)=0.40 mol/L、淋洗6 h条件下,土壤中Pb的去除率最高;EDTA-2Na溶液对Pb质量比高的盐渍化土壤表层中Pb的去除率(67.9%),明显高于Pb质量比低的土壤;经EDTA-2Na溶液淋洗后,相比初始土壤,低盐渍化土壤中盐的质量比增加,高盐渍化土壤中盐的质量比降低;增加淋洗次数虽提高了土壤中Pb的去除率(84.9%),但增加了土壤的盐渍化程度.在最佳条件下,使用EDTA-2Na溶液淋洗盐渍化Pb污染土壤,可有效去除土壤中的Pb,但要考虑对土壤盐渍化程度的影响.
This study focuses on the farmland soil of Zhenhe Village,a typical agricultural irrigation area in Ningxia.Using a combination of batch experiments and soil column experiments,it investigates the effects of the type,concentration,dosage,and leaching duration of leaching agents on the removal rate of Pb in simulated Pb-contaminated soil.Soil column simulation experiments were conducted to study the remediation of Pb-contaminated soils with different Pb contents and salinization levels using the leaching method.The results show that disodium ethylenediaminetetraacetate(EDTA-2Na)solution achieves the highest Pb removal rate in saline soils.For 1 g of soil,under the conditions of 10 mL of EDTA-2Na solution with a concentration of 0.4 mol/L leached for 6 hours,the Pb removal rate in the soil is maximized.The removal rate of Pb using EDTA-2Na solution is significantly higher in high-Pb saline soils(67.9%)compared to soils with low Pb content.After EDTA-2Na leaching,the total salt content in low-salinity soils increases compared to the initial soil,whereas in high-salinity soils,the total salt content decreases.Although increasing the number of leaching treat-ments improves the Pb removal rate in soil(84.9%),it also increases soil salinization.Under optimal condi-tions,leaching saline Pb-contaminated soil with EDTA-2Na solution can effectively remove Pb from the soil;however,the impact on soil salinization must be taken into account.
马进兰;张玲;陈星宇;王莹
宁夏大学 生态环境学院,宁夏 银川 750021||宁夏大学 西北退化生态系统恢复与重建教育部重点实验室,宁夏 银川 750021宁夏大学 生态环境学院,宁夏 银川 750021||宁夏大学 西北退化生态系统恢复与重建教育部重点实验室,宁夏 银川 750021宁夏大学 生态环境学院,宁夏 银川 750021||宁夏大学 西北退化生态系统恢复与重建教育部重点实验室,宁夏 银川 750021宁夏大学 生态环境学院,宁夏 银川 750021||宁夏大学 西北退化生态系统恢复与重建教育部重点实验室,宁夏 银川 750021
资源环境
化学淋洗法盐渍化土壤Pb污染乙二胺四乙酸二钠(EDTA-2Na)溶液
chemical leaching methodsalinized soillead pollutiondisodium ethylenediaminetetraacetic acid solution
《宁夏大学学报(自然科学版中英文)》 2026 (2)
177-184,8
国家自然科学基金资助项目(42007300)宁夏自然科学基金资助项目(2022AAC03037)宁夏回族自治区重点研发计划(引才专项)项目(2024BEH04046)宁夏回族自治区农业资源环境监测与保护项目(2130135)
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