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低灰熔点煤的熔融特性研究分析OA

Study on the Fusion Characteristics of Low Ash-Fusion-Temperature Coals

中文摘要英文摘要

低灰熔点煤燃烧过程中会发生严重熔融现象,导致了受热面的沾污,长期运行会产生严重的结渣现象,因而研究低灰熔点煤的熔融特性具有十分重要的意义.选用 3 种不同灰含量的低灰熔点煤和 1 种高灰熔点石炭煤进行了分析.根据灰成分计算了不同的结渣指标并与灰熔融特征温度进行了拟合.在不同温度下制备了煤粉灰,研究了灰中碱/碱土金属的含量变化规律以及对结渣特性预测的影响.研究发现:低灰熔点煤中钙和铁金属含量要远高于高灰熔点煤;酸碱比、硅比、硅铝比、铁钙比和综合指数都与灰软化温度呈现一定的关系,但综合指数和硅铝比与灰软化温度具有更好的线性关系.高温黏度实验表明:当烟气温度降至灰流动温度时,灰的黏度迅速大幅增加,导致其粘附在受热面上.随着煤粉灰制备温度的增加,灰中钠金属含量快速减少,而铁和钙相对含量则呈现增加趋势,镁含量呈先增加后降低的趋势.

During the combustion of low ash-fusion-temperature coal,severe melting phenomena occur,leading to the fouling of heat exchange surfaces.Long-term operation can result in serious slagging.Therefore,studying the melting characteristics of low ash-fusion-temperature coal is of significant importance.Three different low ash-fusion-temperature coals with varying ash contents were analyzed,along with a high ash-fusion-temperature coal.The slagging indices were calculated based on the ash composition and fitted with the ash fusion temperature.Coal ash was prepared at different temperatures,and the variations in the content of alkali/alkaline earth metals in the ash were investigated,along with their influence on the prediction of slagging characteristics.The study found that the content of calcium and iron metals in low ash-fusion-temperature coals was much higher than in high ash-fusion-temperature coal.The acid-base ratio(B/A),silica ratio(G),silica-alumina ratio,iron-calcium ratio,and a comprehensive index all showed a certain relationship with the ash soft temperature.However,the comprehensive index and the silica-alumina ratio had a better linear relationship with the ash soft temperature.High-temperature viscosity experiments showed that when the flue gas temperature decreased to the ash flow temperature,the viscosity of the ash increased rapidly,leading to its adhesion to heat exchange surfaces.As the coal ash preparation temperature increased,the sodium content in the ash decreased rapidly,while the relative content of iron and calcium showed an increasing trend.The magnesium content first increased and then decreased.

沈兰;于洁;成丽波;秦荣江;程型;赵义;陈雪林;陈辉;王秀军;李明洲

国能织金发电有限公司,贵州 毕节 552106华中科技大学 煤燃烧与低碳利用全国重点实验室,湖北 武汉 430074国能织金发电有限公司,贵州 毕节 552106国能织金发电有限公司,贵州 毕节 552106国能织金发电有限公司,贵州 毕节 552106国能织金发电有限公司,贵州 毕节 552106国能织金发电有限公司,贵州 毕节 552106国能南京电力试验研究有限公司,江苏 南京 210046国能南京电力试验研究有限公司,江苏 南京 210046华中科技大学 煤燃烧与低碳利用全国重点实验室,湖北 武汉 430074

能源科技

低灰熔点煤结渣灰熔融碱金属高温黏度

low ash-fusion-temperature coalslaggingash fusionalkali metalshigh-temperature viscosity

《锅炉技术》 2026 (2)

49-54,6

国家自然科学基金面上项目(52076091)国家能源集团科技创新项目(GJNY-24-69)

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