首页|期刊导航|中国造纸学报|羧甲基纤维素钠/羧甲基壳聚糖气凝胶基湿气发电装置的制备及其性能研究

羧甲基纤维素钠/羧甲基壳聚糖气凝胶基湿气发电装置的制备及其性能研究OA

Study on Preparation of Sodium Carboxymethyl Cellulose/Carboxymethyl Chitosan Aerogel-based Moist Electri city Generation Device and Its Performance

中文摘要英文摘要

本研究以羧甲基纤维素钠(CMC-Na)和羧甲基壳聚糖(CMCS)为原料,制备了 CMC-Na/CMCS气凝胶;将其与多孔铝网、铜箔组装,设计开发了具有"三明治"结构并兼具高效湿气捕获与转化能力的新型湿气发电装置(MEGs),考察了制得CMC-Na/CMCS气凝胶基MEGs的湿气发电性能.结果表明,CMC-Na与CMCS间成功发生交联反应,使制得的CMC-Na/CMCS气凝胶具备三维网络结构和均匀的孔隙.在温度45 ℃、相对湿度80%的条件下,CMC-Na/CMCS气凝胶基MEGs能输出的最大稳定开路电压(Voc)高达0.90 V,最大稳定短路电流(Jac)高达2.6μA.在日常环境条件(温度25~40 ℃,相对湿度55%~75%)下,CMC-Na/CMCS气凝胶基MEGs能够实现长达24h的持续电压输出,Voc稳定在0.43~0.79V范围内,显示出良好的环境适应性和稳定性.

In this study,carboxymethyl cellulose sodium(CMC-Na)and carboxymethyl chitosan(CMCS)were used as raw materials to pre-pare CMC-Na/CMCS aerogel.Then the aerogel was assembled with a porous aluminum mesh and copper foil to construct a novel moist elec-tricity generation devices(MEGs)featuring a'sandwich'structure that integrated both efficient moisture capture and conversion capabili-ties.The performance of moist electricity generation of prepared CMC-Na/CMCS aerogel-based MEGs was evaluated.The results indicated that the successful cross-linking between CMC-Na and CMCS was occurred,endowing the CMC-Na/CMCS aerogel with a three-dimensional network structure and uniform pore.Under conditions at 45℃ and relative humidity of 80%,the CMC-Na/CMCS aerogel-based MEGs achieved a maximum stable open-circuit voltage(Voc)of 0.90 V and a short-circuit current(Isc)of 2.6 μA.Under normal environmental condi-tions(temperature of 25~40℃,relative humidity of 55%~75%),the CMC-Na/CMCS aerogel-based MEGs sustained continuous voltage out-put for up to 24 h,with Voc stabilizing between 0.43 V and 0.79 V,demonstrating excellent environmental adaptability and operational stability.

向钟;田秀枝;李宇航;焦欣烨;杜依纯;蒋学

陕西科技大学轻工科学与工程学院,陕西西安,710021陕西科技大学轻工科学与工程学院,陕西西安,710021陕西科技大学轻工科学与工程学院,陕西西安,710021陕西科技大学轻工科学与工程学院,陕西西安,710021陕西科技大学轻工科学与工程学院,陕西西安,710021陕西科技大学轻工科学与工程学院,陕西西安,710021

轻工纺织

羧甲基纤维素羧甲基壳聚糖气凝胶湿气发电装置

carboxymethyl cellulosecarboxymethyl chitosanaerogelmoist electricity generation devices(MEGs)

《中国造纸学报》 2026 (1)

30-36,7

陕西科技大学自然科学前沿研究基金(2020XSGG-07)陕西省重点研发计划(2022GY-278)陕西省自然科学基础研究计划(2023-JC-YB-104)广西清洁化制浆造纸与污染控制重点实验室开放基金(2023GXZZKF36).

10.11981/j.issn.1000-6842.2026.01.30

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