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锂离子电池锡基负极材料的改性研究进展OA

Advances in modification research of tin-based anode materials for lithium-ion batteries

中文摘要英文摘要

随着电动汽车和储能设备对高能量密度、高倍率、长寿命电池的需求不断增加,开发具有优异电化学性能的锂离子电池负极材料是必然趋势.锂离子电池因其能量密度高、输出功率稳定、长寿命等在新能源领域迅速发展.作为最有前景的替代传统石墨负极的锂离子电池锡基负极材料、包括锡金属基材料、锡基氧化物和锡基硫化物,因其具有较高的比容量、安全性高、环境友好等优点备受关注,被认为是下一代最有前途的锂离子电池的负极材料.然而,在循环过程中锡基负极材料会有巨大的体积膨胀、粉化和团聚现象,这成为其实际应用的最大阻碍.本文系统阐述锡基负极材料的最新进展,深入讨论锡基负极材料的改性研究.最后,指出当前开发锡基负极材料所面临的挑战和问题,并展望锂离子电池负极材料未来研究的方向.

With the increasing demand of electric vehicles and energy storage equipment for high energy density,high rate and long life batteries,the development of lithium-ion battery anode materials with excellent electrochemical performance is an inevitable trend.Lithium-ion batteries develop rapidly in the field of new energy due to their high energy density,stable output power and long life.As the most promising alternative to traditional graphite anode lithium-ion battery tin-based anode materials,tin-based anode material include tin metal-based material,tin-based oxide and tin-based sulfide,and because of its high specific capacity,high safety,environmental friendly attention,it is considered to be the most promising anode material for the next generation of lithium-ion batteries.However,the huge volume expansion,pulverization and agglomeration of tin-based anode materials in the cycle process become the biggest obstacle to its practical application.In this review,the latest progress of tin-based anode materials was systematically described.The modification of tin-based anode materials was discussed in detail.Finally,the challenges and problems in the development of tin-based anode materials were pointed out,and the future research direction of anode materials for lithium-ion batteries was prospected.

刘辉;王树众;张文进;包蕊;景泽锋

西安交通大学 能源与动力工程学院,陕西 西安 710049西安交通大学 能源与动力工程学院,陕西 西安 710049西安交通大学 能源与动力工程学院,陕西 西安 710049西安交通大学 能源与动力工程学院,陕西 西安 710049西安交通大学 能源与动力工程学院,陕西 西安 710049

信息技术与安全科学

锂离子电池锡基负极材料体积膨胀改性研究

lithium-ion batterytin-based anode materialvolume expansionmodification research

《化学工程》 2026 (3)

1-7,7

国家自然科学基金资助项目(52476160)陕西省重点研发计划(2024GX-YBXM-314)

10.3969/j.issn.1005-9954.2026.03.001

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