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四川雅安某含碳镁质磷矿浮选试验研究OA

Experimental study on flotation of a carbon-containing magnesian phosphate rock in Ya'an,Sichuan Province

中文摘要英文摘要

含碳质胶磷矿的浮选难度较大,主要归因于碳质污染物的双重影响:一方面,碳质在矿物表面的覆盖导致磷矿物与脉石(如白云石、方解石)表面性质均一化,严重削弱了浮选选择性;另一方面,碳质不仅增大了药剂消耗,其残留还会直接影响后续磷酸加工的产品质量.然而,现有研究对浮选前碳质预脱除的关键环节关注不足,相关技术仍处于初步探索阶段,严重制约了含碳质胶磷矿的高效利用.本文以四川雅安某含碳镁质胶磷矿为研究对象,通过反浮选试验优化工艺参数,以TC-2为脱碳剂、硫酸为抑制剂、MG-7为捕收剂,结合"2粗1精2扫"闭路流程,考察了磨矿细度、脱碳剂用量、抑制剂及捕收剂条件对浮选指标的影响.结果表明:当磨矿细度为-0.074 mm占70.31%、脱碳剂TC-2用量为100 g/t时,精矿P2O5品位显著提升至28.03%,回收率达83.37%,尾矿品位降至9.10%;脱碳预处理有效降低了精矿中有机质质量分数(从0.83%降至0.59%),验证了该工艺对含碳质胶磷矿的分选适应性.研究成果可为同类磷矿的高效开发与利用提供技术参考.

The flotation of carbonaceous collophane is difficult,mainly due to the dual effects of carbonaceous pollu-tants.On the one hand,the coverage of carbonaceous pollutants on the surface of minerals leads to the homogenization of the surface properties of phosphate minerals and gangues(such as dolomite and calcite),which seriously weakens the flotation selectivity.On the other hand,carbon not only increases the ineffective consumption of the agent,but also its residue will directly affect the product quality of the subsequent phosphoric acid processing.However,the existing research pays insufficient attention to the key links of pre-removal of carbonaceous matter before flotation,and the related technologies are still in the preliminary exploration stage,which seriously restricts the efficient utiliza-tion of carbonaceous collophane.In this paper,a carbon-containing magnesium collophane in Ya'an,Sichuan Province was taken as the research object.The process parameters were optimized by reverse flotation test.TC-2 was used as a decarburization agent,sulfuric acid was used as an inhibitor,and MG-7 was used as a collector.Combined with the closed-circuit process of'2 roughing,1 cleaning and 2 scavenging',the effects of grinding fineness,decarburization agent dosage,inhibitor and collector conditions on flotation indexes were investigated.The results show that when the grinding fineness is-0.074 mm accounting for 70.31%and the amount of decarburization agent TC-2 is 100 g/t,the P2O5 grade of concentrate is significantly increased to 28.03%,the recovery rate is 83.37%,and the tailings grade is reduced to 9.10%.The decarburization pretreatment effectively reduced the mass fraction of organic matter in the concentrate(from 0.83%to 0.59%),which verified the adaptability of the process to the separation of carbonaceous collophane.The research results can provide technical reference for the efficient development and utilization of similar phosphate rock.

邓敏;魏娜;陈骞;李洪强

武汉工程大学 资源与安全工程学院,湖北 武汉 430073||磷矿及其共伴生资源绿色高效开发利用全国重点实验室,湖北 武汉 430073武汉工程大学 资源与安全工程学院,湖北 武汉 430073||磷矿及其共伴生资源绿色高效开发利用全国重点实验室,湖北 武汉 430073武汉工程大学 资源与安全工程学院,湖北 武汉 430073||磷矿及其共伴生资源绿色高效开发利用全国重点实验室,湖北 武汉 430073武汉工程大学 资源与安全工程学院,湖北 武汉 430073||磷矿及其共伴生资源绿色高效开发利用全国重点实验室,湖北 武汉 430073

矿业与冶金

胶磷矿反浮选含碳镁质磷矿闭路流程条件试验预处理

collophanereverse flotationcarbon-containing magnesian phosphate rockclosed circuit processcon-ditional testpretreatment

《化工矿物与加工》 2026 (3)

21-30,10

10.16283/j.cnki.hgkwyjg.2026.03.004

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