刺梨多酚贮藏、加工稳定性及降解动力学研究OA
Storage,processing stability and degradation kinetics of Rosa roxbrughii Tratt polyphenols
[目的]探究刺梨游离酚与结合酚在不同贮藏、加工条件下的稳定性差异,并分析热降解动力学特征,为刺梨多酚在食品及功能性食品中的应用提供理论参考.[方法]从贵州刺梨中提取游离酚和结合酚,用福林酚法测定其在不同温度、光照、pH、氧化剂、还原剂、防腐剂等条件下多酚含量的变化,用零级、一级动力学方程分析其热降解动力学,探究稳定性差异.[结果]氧化剂H2O2、还原剂Na2SO3对多酚稳定性的影响较大,保存率显著下降,而在避光、酸性(pH<6.0)、50 ℃、有防腐剂的环境下刺梨多酚稳定性较好,且结合酚比游离酚表现出更好的稳定性.此外,刺梨游离酚与结合酚的降解均符合一级动力学模型,进一步探究发现游离酚的热降解为吸热非自发反应.[结论]刺梨多酚产品宜在低温酸性条件进行加工贮藏,以保障产品品质.此外,还需结合不同多酚形态的特性及应用需求选择开发方向.
[Objective]Differences in the stability of free phenols and bound phenols in Rosa roxburghii Tratt(RRT)under different storage and processing conditions,and their thermal degradation kinetics characteristics were investigated,to provide a theoretical reference for the application of RRT polyphenols in food and functional food.[Method]Free and bound phenols were extracted from Guizhou RRT,and then detected by Folin-Ciocalteu method under various conditions such as temperature,light,pH,oxidant,re-ducing agent and preservatives for exploring the stability differences.Then the thermal degradation kinetics were further analyzed by zero and first order kinetic equations.[Result]The oxidant H2O2 and reducing agent Na2SO3 negatively affected the stability of poly-phenols,causing significant decreases in the retention rate,however,darkness,acidity(pH<6.0),50 ℃ and preservatives were contributed to good stability;bound polyphenols exhibited better stability than free phenols.In addition,the degradation of free poly-phenols and bound polyphenols in RRT both was in accord with the first order kinetic model.Further investigation found that thermal degradation of free polyphenols was an endothermic and non-spontaneous reaction.[Conclusion]Products containing RRT polyphe-nols are recommended to be processed and stored under low-temperature and acidic conditions to ensure product quality.Further de-velopment should consider the characteristics of various polyphenol forms and specific application requirements.
陈艳;王亚萍;戴思敏;孟令帅;刘晓燕;周笑犁
贵阳学院食品科学与工程学院,贵州贵阳 550005贵阳学院食品科学与工程学院,贵州贵阳 550005贵阳学院食品科学与工程学院,贵州贵阳 550005贵阳学院食品科学与工程学院,贵州贵阳 550005贵阳学院食品科学与工程学院,贵州贵阳 550005贵阳学院食品科学与工程学院,贵州贵阳 550005
轻工纺织
刺梨多酚稳定性降解动力学加工条件贮藏条件
Rosa roxburghiipolyphenolsstabilitydegradation kineticsprocessing conditionstorage condition
《福建农林大学学报(自然科学版)》 2026 (2)
280-290,11
贵州省生态特色食品新质化加工与贮藏重点实验室[黔科合平台(ZSYS[2025]023)]国家自然科学基金项目(32060536)贵州省科技计划项目(黔科合基础-ZK[2022]重点005黔科合支撑[2024]一般021)贵阳学院研究生科研基金项目(GYU-YJS[2023]-02).
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