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不同纳米铁系添加剂对餐厨垃圾厌氧消化特性的影响OA

Effects of Different Nano-iron-based Additives on Anaerobic Digestion Characteristics of Kitchen Waste

中文摘要英文摘要

为考察不同纳米铁系添加剂对餐厨垃圾厌氧消化特性的影响,向餐厨垃圾中温批次厌氧消化系统中分别添加1 g·L-1的纳米铁系添加剂即纳米零价铁(nZVI)、纳米三氧化二铁(Fe2O3 NPs)和纳米四氧化三铁(Fe3O4 NPs).发酵指标、动力学和微生物分析结果表明:添加3种纳米铁系物均能改善产甲烷性能,但nZVI的作用效果最明显.投加nZVI后,累积甲烷产量为394.9 mL·g-1VS,较对照组提高了 12.5%.此外,其理论最大产甲烷潜力提升10.1%,最大产甲烷速率提升14.8%,延滞时期缩短47.8%,末期沼液中挥发性脂肪酸降低39.2%.产气高峰时,投加nZVI、Fe2O3 NPs和Fe3O4 NPs的沼液中Fe2+浓度分别比对照提升53.1%、50.5%和25.2%,电子传递活性分别比对照提升了 32.9%、10.4%和-16.3%,氢营养型产甲烷古菌属Methanobacterium相对丰度分别比对照提高76.7%、5.1%和31.8%.综上,添加3种纳米铁系物均能通过提高沼液中Fe2+浓度和促进Methanobacterium的富集,从而缩短产甲烷延滞期,提升产甲烷速率,降低末期VFA累积,并最终提高甲烷产量.

To investigate the effects of different nano-iron-based additives on the anaerobic digestion characteristics of kitch-en waste,1 g·L-1of nZVI,Fe2O3 NPs,and Fe3O4 NPs were severally added to the batched anaerobic digestion system un-der mesophilic condition.The results of fermentation indicators,kinetics,and microbial analysis showed that adding all three nano-iron-based substances could improve the methane production performance,with nZVI showed the most signifi-cant effect.After adding nZVI,the cumulative methane production was 394.9 mL·g-1VS,which was 12.5%higher than that of the control group.Additionally,its theoretical maximum methane production potential increased by 10.1%,the maximum methane production rate increased by 14.8%,the lag period was shortened by 47.8%,and the volatile fatty acids in the final slurry decreased by 39.2%.At the peak of biogas production,the concentrations of Fe2+in the slurry with nZVI,Fe2O3 NPs,and Fe3O4 NPs were 53.1%,50.5%,and 25.2%higher than that of the control group,respec-tively.The electron transfer activity was 32.9%,10.4%,and-16.3%higher than that of the control group,respective-ly.The relative abundance of hydrogenophilic methanogenic archaea genus Methanobacterium was 76.7%,5.1%,and 31.8% higher than that of the control group.In summary,adding all three nano-iron-based substances could increase the concentration of Fe2+in the slurry and promote the enrichment of Methanobacterium,thereby shortening the methane pro-duction lag period,increasing the methane production rate,reducing the final VFA accumulation,and ultimately increasing the methane yield.

吴彤彤;孙辰;曹卫星

浙江理工大学 生命科学与医药学院,浙江 杭州 310018||嘉兴大学 生物与化学工程学院,浙江嘉兴 314001嘉兴大学 生物与化学工程学院,浙江嘉兴 314001嘉兴大学 生物与化学工程学院,浙江嘉兴 314001

农业科技

餐厨垃圾纳米铁系添加剂厌氧消化微生物群落结构

kitchen wastenano iron-based additivesanaerobic digestionmicrobial community structure

《中国沼气》 2026 (1)

32-39,8

嘉兴市科技局项目(2023AY11054)浙江省自然科学基金(LY22E060002).

10.20022/j.cnki.1000-1166.2026010032

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