醇氧化反应中非均相催化剂的界面调控研究进展OA

Carbonyl compounds are extensively utilized in pharmaceutical and fine chemical industries.The selective oxidation of alcohols serves as an important pathway for synthesizing carbonyl compounds.However,conventional thermal catalytic methods suffer from harsh reaction conditions,low target product selectivities and environmental concerns.Heterogeneous catalysts have demonstrated unique advantages in high-efficiency selective oxidation of alcohols,and their catalytic performances depend on geometric and electronic configurations of the catalyst.Interface engineering enables precise optimization of alcohol adsorption and activation processes through modulation of interfacial active sites.The regulatory mechanisms and strategies of interface engineering in thermocatalytic heterogeneous alcohol oxidation reactions were reviewed.The mechanisms of interfacial modulation of non-homogeneous catalysts by electronic and geometrical effects were discussed and the interface-based modulation methodologies were analyzed.In addition,a brief discussion of the impact of artificial intelligence-assisted approaches on catalyst design was provided and the future development direction of designing interfacial active sites in alcohol oxidation reactions via interface engineering was prospected.