低密度铵胺炸药的制备与性能研究OA
Study on the Preparation and Properties of Low-density Ammonium Amine Explosives
为满足光面爆破、预裂爆破等工程对低密度炸药的需求,以质量分数20%亚硝酸钠溶液作为发泡剂,对铵胺炸药进行化学发泡,制得不同密度的炸药样品;采用光学显微技术结合Cellpose图像分割算法与Fiji图像分析平台,对铵胺炸药敏化气泡增长速率及尺寸分布进行微观表征与分析;使用爆速仪和铅柱压缩法,分别对爆速和猛度进行测试.结果表明,当铵胺炸药中发泡剂质量分数由1.6%增至3.2%时,炸药密度由0.61g/cm3降至0.33g/cm3,初始发泡速率从0.080g/(cm3·min)增至0.106g/(cm3·min),炸药密度与气泡尺寸均在发泡15min后变化缓慢;敏化气泡分布宽度从35.26μm增至62.26μm,分散指数由0.69增至0.89,平均尺寸从56.80μm增至81.08μm,分布范围变宽,均匀性变差;炸药爆速、猛度均随密度减小而下降,其中爆速从3191.35m/s降至2 215.26m/s,降幅为30.6%;猛度由24.96mm降至22.83 mm,降幅为8.5%.由此表明,在铵胺炸药中通过调节发泡剂的添加量,可实现低密度铵胺炸药的制备及性能调控.
To meet the demand for low-density explosives in smooth blasting and presplitting blasting projects,the ammonium amine explosive was chemically foamed using a 20%sodium nitrite solution as a foaming agent to prepare the explosive sam-ples with different densities.The growth rate and size distribution of sensitized bubbles in the ammonium amine explosive were characterized and analyzed at the microscopic level using optical microscopy combined with the Cellpose image segmentation algorithm and the Fiji image analysis platform.Detonation velocity and brisance were tested using a detonation velocimeter and the lead cylinder compression test,respectively.The results show that when the content of the foaming agent in the ammonium amine explosive increases from 1.6%to 3.2%,the explosive density decreases from 0.61 g/cm3 to 0.33 g/cm3,and the in-itial foaming rate increases from 0.080g/(cm3·min)to 0.106g/(cm3·min).Both the explosive density and bubble size change slowly after 15 minutes of foaming.The distribution width of sensitized bubbles increases from 35.26μm to 62.26μm,the dispersion index increases from 0.69 to 0.89,and the average bubble size increases from 56.80μm to 81.08μm,indi-cating a wider distribution range and poorer uniformity.The detonation velocity and brisance of the explosives decreases with the reduction in density.Specifically,the detonation velocity decreases from 3 191.35m/s to 2215.26m/s,a reduction of 30.6%,while the brisance decreases from 24.96 mm to 22.83 mm,a reduction of 8.5%.These findings demonstrate that by adjusting the amount of foaming agent added,the preparation and performance regulation of low-density ammonium amine explosive can be achieved.
汪泉;管仲北;王焕;黄文尧;茆亚平;童凯;王俊豪;袁文婕
安徽理工大学化工与爆破学院,安徽淮南 232001安徽理工大学化工与爆破学院,安徽淮南 232001葛洲坝易普力广西威奇化工有限责任公司,广西柳州 545000安徽理工大学化工与爆破学院,安徽淮南 232001安徽理工大学化工与爆破学院,安徽淮南 232001安徽理工大学化工与爆破学院,安徽淮南 232001安徽理工大学化工与爆破学院,安徽淮南 232001安徽理工大学化工与爆破学院,安徽淮南 232001
军事科技
应用化学低密度炸药铵胺炸药发泡剂爆速猛度
applied chemistrylow-density explosiveammonium amine explosivefoaming agentdetonation velocitybri-sance
《火炸药学报》 2026 (2)
191-199,9
安徽高校自然科学研究重大项目(No.2024AH040070)安徽理工大学校级质量工程项目(No.xjkcszjy2025212)
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