助剂对熔铸炸药力学性能改善的研究进展OA
Research Progress on the Improvement of Mechanical Properties of Melt-cast Explosives by Additives
系统综述了熔铸炸药力学性能改性的研究进展,重点探讨了纤维、纳米粒子、结晶及聚合物这4类力学改性助剂的作用机理与应用效果.研究结果表明,各类改性剂均能通过不同途径提升熔铸炸药的力学性能,但也分别存在局限性:纤维改性剂虽可增强抗压强度,但易导致抗拉强度下降且工艺适配性受限;纳米粒子改性剂在分散均匀性与界面机理方面仍存在挑战;结晶改性剂成本较高且对多组分体系的调控机制尚不明确.相比之下,含能热塑性弹性体(ETPE)展现出更优越的综合性能,不仅能够通过结构设计实现强韧化与钝感化,还具备良好的工艺适应性和可回收性,是当前最具潜力的改性方向.指出未来研究应着重开发具有宽温域适应性、优异工艺兼容性、高能量-低感度协同、环境耐久性与智能响应功能的新型ETPE体系,并推动其绿色合成与循环利用,以促进熔铸炸药在高安全、长寿命及可持续方向的发展.附参考文献93篇.
The research progress on modifying the mechanical properties of melt-cast explosives was systematically reviewed,with an emphasis on investigating the mechanisms and application effects of four different types of mechanical modification addi-tives:fibers,nanoparticles,crystals,and polymers.Research has demonstrated that various additives can improve the me-chanical properties of melt-cast explosives in different pathways,but they also have limitations.For instance,while fiber modi-fiers can enhance compressive strength,they can also easily result in a decrease in tensile strength and limited process adapta-bility.Nanoparticle additives still face challenges in dispersion uniformity and interface mechanism.Crystalline additives are ex-pensive,and the regulatory mechanism for multi-component system is still unclear.By contrast,energetic thermoplastic elasto-mers(ETPEs)are the most promising additives owing to their superior integrated performance,which includes not only the a-bility to achieve toughness and desensitization through structural design but also good process adaptability and recyclability.In order to advance the development of melt-cast explosives in the direction of high safety,long life,and sustainability,future re-search should concentrate on developing new ETPE systems with a wide temperature range adaptability,excellent process com-patibility,high energy-low sensitivity synergy,environmental durability,and intelligent response functions,as well as promo-ting their green synthesis and recycling melt-cast.With 93 references were attached.
郭前进;潘启;齐蕾;王浩;郭学永
北京理工大学机电学院,北京 100081北京理工大学机电学院,北京 100081山东特种工业集团有限公司,山东淄博 255201北京理工大学机电学院,北京 100081北京理工大学机电学院,北京 100081
军事科技
材料力学熔铸炸药力学改性纤维结晶纳米粒子含能热塑性弹性体功能助剂
material mechanicsmelt-cast explosivesmechanical modificationfiberscrystallizationnanoparticlesener-getic thermoplastic elastomersfunctional additives
《火炸药学报》 2026 (2)
107-126,20
国家自然科学基金面上项目(No.22175026)
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