首页|期刊导航|化学试剂|改性生物炭吸附水体中微塑料的研究:改性方法和去除机理

改性生物炭吸附水体中微塑料的研究:改性方法和去除机理OA

Engineered Biochar for Microplastic Removal from Water:Modification Strategies and Mechanisms

中文摘要英文摘要

微塑料作为一种新兴的全球性环境污染物,在水体中广泛分布,对生态系统和人类健康构成严重威胁.生物炭因其独特的孔隙结构和表面性质,在环境污染治理中展现出广阔前景.然而,原状生物炭对微塑料的吸附存在效率低、容量有限等问题,而功能化改性可显著提升其吸附性能.系统综述了改性生物炭去除水体中微塑料的研究进展.重点阐述了化学改性(如金属负载、酸碱处理)与物理改性(如气体活化)等方法,通过调控生物炭的孔隙结构、表面电荷和官能团,增强其与微塑料的作用.同时,深入剖析了物理截留、静电吸引、氢键及表面络合等多种吸附机制.进一步探讨了生物炭自身特性、微塑料性质(如类型、粒径)以及环境因素(如pH值、溶解性有机质)对吸附过程的综合影响.此外,简要评述了改性生物炭的再生技术与实际应用所面临的挑战,包括制备成本、长期生态安全性及在复杂水体环境中的稳定性问题.旨在为改性生物炭材料的优化设计及其在微塑料污染治理中的工程应用提供理论参考.

Microplastics are an emerging global environmental pollutant that are widely distributed in aquatic environments and have attracted increasing attention due to their potential ecological and health impacts.Biochar shows great promise in environmental pollution remediation due to its unique pore structure and surface properties.However,the adsorption of microplastics by raw biochar was often limited by low efficiency and low capacity,and various modification strategies have been developed to improve its effectiveness.This review systematically summarized recent advances in the removal of microplastics from aqueous environments using modified biochar.Chemical modification methods,including metal impregnation and acid or alkali treatment,as well as physical modification approaches such as steam activation,were discussed with respect to their effects on the pore structure,surface charge,and functional groups of biochar.The main adsorption mechanisms,such as physical interception,electrostatic attraction,hydrogen bonding,and surface complexation,were also discussed in detail.Furthermore,the influences of biochar properties,microplastic characteristics(e.g.,type,size),and environmental factors(e.g.,pH,dissolved organic matter)on the adsorption process were examined.Additionally,this review briefly addressed regeneration techniques for modified biochar and the challenges of practical application,including preparation cost,long-term environmental safety,and stability in complex aqueous environments.This review provided a reference for the design and application of modified biochar material for microplastic removal in aquatic environments.

罗堂;李锦雅;纪鹏宇;范世锁

安徽农业大学资源与环境学院,安徽 合肥 230036安徽农业大学资源与环境学院,安徽 合肥 230036安徽农业大学资源与环境学院,安徽 合肥 230036安徽农业大学资源与环境学院,安徽 合肥 230036

化学化工

生物炭微塑料改性方法吸附机制影响因素实际挑战

biocharmicroplasticsmodification methodsadsorption mechanismsinfluencing factorspractical challenges

《化学试剂》 2026 (3)

1-11,11

国家自然科学基金项目(51809001)安徽省自然科学基金项目(2408085MD089).

10.13822/j.cnki.hxsj.2025.0298

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