光催化材料的熔盐法制备研究进展OA
Progress of the synthesis of photocatalytic materials by molten salt methods
在当前全球能源危机与环境污染问题日益加剧的背景下,光催化技术因其绿色、可再生的特点,有望成为解决能源与环境问题的重要手段.目前,制备光催化材料的常用方法包括传统固相法和湿化学方法,但这些方法往往难以同时兼顾高质量与高产量,这限制了其在光催化技术的广泛应用.相比之下,熔盐法因其操作简单、经济效益高和易于大规模生产等优点,正受到研究者的广泛关注.为此,首先分析了传统合成方法的局限性;接着,基于熔盐的分类与特性,探讨了单盐与混合盐的类型选择依据,以及它们的熔点、潮解性、安全性等特性;然后,从形貌调控、结晶度提升和元素掺杂三个维度,系统阐述了熔盐法优化光催化材料性能的内在机制,并进一步综述了该方法在金属氧化物、金属硫化物、碳氮化合物和钙钛矿等多种光催化材料合成中的实际应用;最后,针对当前熔盐法在成本和环境友好方面面临的挑战,提出未来应致力于开发更具环保性和经济性的熔盐体系,以推动该方法在光催化材料合成领域的可持续发展.
Against the backdrop of escalating global energy crisis and environmental pollution,photocatalytic technology,owing to its green and renewable characteristics,holds promise as a crucial means to address energy and environmental challenges.Currently,common methods for preparing photocatalytic materials include traditional solid-state methods and wet chemical approaches;however,these methods often struggle to simultaneously achieve both high quality and high yield,thereby limiting the widespread application of photocatalytic technology.In contrast,molten salt method has garnered significant research interest due to its distinct advantages,including simple operation,high economic efficiency,and ease of large-scale production.The inherent limitations of traditional synthesis methods were first analyzed.Subsequently,based on the classification and characteristics of molten salts,the selection criteria for single salts and mixed salts,as well as their melting points,deliquescence,and safety,were discussed.Then,the intrinsic mechanisms through which molten salt methods optimize the performance of photocatalytic materials were systematically elaborated from three dimensions:morphology regulation,crystallinity enhancement,and elemental doping.Furthermore,the practical applications of molten salt method in preparing diverse photocatalytic materials,including metal oxides,metal sulfides,carbon nitrides,and perovskites,were reviewed.Finally,addressing the current challenges molten salt methods face regarding cost and environmental friendliness,it was proposed that future efforts should be focused on developing more environmentally benign and economical molten salt systems to promote the sustainable development of this method in the field of photocatalytic material synthesis.
李玉玲;蒋志强;余浩生;张红英;王潇伊;李覃
中南民族大学催化转化与能源材料化学教育部重点实验室,武汉 430074||中南民族大学湖北省催化材料科学重点实验室,武汉 430074中南民族大学催化转化与能源材料化学教育部重点实验室,武汉 430074||中南民族大学湖北省催化材料科学重点实验室,武汉 430074中南民族大学催化转化与能源材料化学教育部重点实验室,武汉 430074||中南民族大学湖北省催化材料科学重点实验室,武汉 430074中南民族大学催化转化与能源材料化学教育部重点实验室,武汉 430074||中南民族大学湖北省催化材料科学重点实验室,武汉 430074中南民族大学催化转化与能源材料化学教育部重点实验室,武汉 430074||中南民族大学湖北省催化材料科学重点实验室,武汉 430074中南民族大学催化转化与能源材料化学教育部重点实验室,武汉 430074||中南民族大学湖北省催化材料科学重点实验室,武汉 430074
化学化工
熔盐法光催化材料二氧化钛硫化镉钙钛矿
molten salt methodphotocatalyst materialsTiO2CdSperovskite
《中南民族大学学报(自然科学版)》 2026 (3)
289-305,17
国家自然科学基金资助项目(21972171)中南民族大学大学生创新创业训练计划项目(S202510524045)
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