首页|期刊导航|仲恺农业工程学院学报|基于六水氯化钙的复合相变调湿材料的制备及热湿性能的研究

基于六水氯化钙的复合相变调湿材料的制备及热湿性能的研究OA

Preparation and hygrothermal properties of composite phase change humidity control materials based on hexahydrate calcium chloride

中文摘要英文摘要

为研究无机复合相变材料与多孔调湿材料结合后的热湿性能,将六水氯化钙/膨胀石墨复合相变材料与硅藻土相结合,制得了兼具温度和湿度调节功能的复合相变调湿材料.通过干燥器法测得硅藻土的湿缓冲值为3.81 g/m2·%RH,且其具有较快的吸放湿速率.孔径测试表明硅藻土有丰富的介孔结构,比表面积为 57.421 m2/g.DSC测试结果表明复合相变材料的相变温度和潜热分别为 25.36℃和 90.68 J/g.当通过建筑结构胶将硅藻土和复合相变材料粘结后,所得复合相变调湿材料的储热性能基本不受湿度的影响.将复合相变调湿材料应用于广州地区的小房间模型,结果显示该材料能有效降低室内温度和湿度的波动范围,对改善室内热湿环境具有积极作用.

This paper investigates the preparation and hygrothermal properties of a composite phase change humidity control material.Using hexahydrate calcium chloride as the phase change material and expanded graphite as the carrier material,a composite phase change material was prepared through a porous adsorption method.This material was then combined with diatomite to produce a composite phase change humidity control material capable of regulating both temperature and humidity.The findings reveal that diatomite exhibits excellent humidity control capabilities,with a moisture buffer value of 3.81 g/m2·%RH,a specific surface area of 57.421 m2/g.The composite phase change material demonstrates a phase change temperature of 25.36℃and a latent heat of 90.68 J/g,alongside good thermal stability.By examining the thermal storage performance of the composite phase change material under varying humidity conditions,it was discovered that dry diatomite can slow the decline in the thermal properties of the composite phase change material,with the effect being more pronounced with increasing diatomite thickness.When the diatomite and composite phase change material were bonded using building structural adhesive,the thermal storage performance of the composite phase change humidity control material became unaffected by humidity.Applying the prepared composite phase change humidity control material in a small room model in the Guangzhou area demonstrated its effectiveness in reducing fluctuations in indoor temperature and humidity,thereby positively impacting the indoor thermal and humidity environment.

卢衍君;王军;曾织云;谢文敏;叶荣达

仲恺农业工程学院 化学化工学院,广东 广州 510225仲恺农业工程学院 化学化工学院,广东 广州 510225仲恺农业工程学院 化学化工学院,广东 广州 510225仲恺农业工程学院 化学化工学院,广东 广州 510225仲恺农业工程学院 化学化工学院,广东 广州 510225

通用工业技术

六水氯化钙硅藻土相变材料调湿材料热湿调控材料建筑节能

hexahydrate calcium chloridediatomitephase change materialhumidity control materialhygrothermal control materialbuilding energy efficiency.

《仲恺农业工程学院学报》 2026 (2)

35-42,52,9

国家自然科学基金项目(52006250).

10.3969/j.issn.1674-5663.2026.02.005

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