首页|期刊导航|航空材料学报|Al含量对HVOF-NiCrAlY+APS-nYSZ热障涂层热循环行为的影响

Al含量对HVOF-NiCrAlY+APS-nYSZ热障涂层热循环行为的影响OA

Influence of Al content on thermal cycling behavior of HVOF-NiCrAlY+APS-nYSZ thermal barrier coatings

中文摘要英文摘要

NiCrAlY是燃气轮机热障涂层经常采用的金属黏结层材料,本工作研究用于制造燃气轮机两种Al含量的NiCrAlY粉末对 HVOF-NiCrAlY+APS-纳米结构 YSZ(nanostructured YSZ,nYSZ)热障涂层在室温和 1150℃之间热循环行为的影响.结果表明,HVOF-Ni25Cr5Al0.5Y表面 Al2O3-TGO的生长速率低于 HVOF-Ni22Cr10Al1Y.与微米结构YSZ(microstructured YSZ,mYSZ)/mYSZ界面相同,nYSZ/mYSZ界面也可成为裂纹源,导致在 nYSZ层中形成局部裂纹网络.两种 HVOF-NiCrAlY+APS-nYSZ热障涂层的失效方式与传统APS/HVOF-MCrAlY(M=Ni和Co)+APS-mYSZ相同,主要由于靠近HVOF-NiCrAlY/APS-nYSZ界面nYSZ层裂纹扩展与合并,Ni25Cr5Al0.5Y+nYSZ热循环寿命比 Ni22Cr10Al1Y+nYSZ略高.同时,提高 APS-YSZ层中YSZ/YSZ界面结合力,避免YSZ/YSZ界面和APS-YSZ外表面开裂,可以有效提高HVOF-MCrAlY+APS-YSZ热障涂层热循环寿命.

NiCrAlY is a commonly used metallic bond coat material for thermal barrier coating in gas turbines.This study investigates the effect of two NiCrAlY powders with different aluminum contents for gas turbine fabrication on the thermal cycling behavior of HVOF-NiCrAlY+APS-nanostructured YSZ(nYSZ)thermal barrier coatings(TBCs)within the temperature range from room temperature to 1150℃.The results show that the growth rate of the Al2O3 thermally grown oxide(TGO)on the surface of HVOF-Ni25Cr5Al0.5Y is lower than that of HVOF-Ni22Cr10Al1Y.Similar to the microstructured YSZ(mYSZ)/mYSZ interface,the nYSZ/mYSZ interface can also act as a crack initiation site,leading to the formation of a local crack network in the nYSZ layer.The failure mechanism of two HVOF-NiCrAlY+APS-nYSZ TBCs is consistent with that of the traditional APS/HVOF-MCrAlY(M=Ni and Co)+APS-mYSZ system,which is mainly attributed to the propagation and coalescence of cracks in the nYSZ layer adjacent to the HVOF-NiCrAlY/APS-nYSZ interface.The thermal cycling lifetime of the Ni25Cr5Al0.5Y+APS-nYSZ coating is slightly longer than that of the Ni22Cr10Al1Y+APS-nYSZ coating.Meanwhile,it can effectively improve the thermal cycling life of HVOF-MCrAlY+APS-YSZ TBCs to increase the bonding strength of the YSZ/YSZ interface in the APS-YSZ layer and avoid cracking at the YSZ/YSZ interface and the outer surface of the APS-YSZ.

李超;程玉贤;黎红英;王璐;陈卫杰

昆明理工大学 材料科学与工程学院,昆明 650093中国航发沈阳黎明航空发动机有限责任公司 技术中心,沈阳 110043西北工业大学 动力与能源学院,西安 710129||中国航发航空科技股份有限公司,成都 610500辽宁材料实验室 燃氢防护技术研究所,沈阳 110167辽宁材料实验室 燃氢防护技术研究所,沈阳 110167

通用工业技术

燃气轮机热障涂层HVOF-NiCrAlYAl含量APS-nYSZ热循环行为

gas turbinethermal barrier coatingHVOF-NiCrAlYAl contentAPS-nYSZthermal cycling behavior

《航空材料学报》 2026 (3)

87-96,10

国家青年科学基金(52401093)辽宁省科技重大专项(2024JH1/11700039)辽宁省中央引导地方科技发展资金联合基金(IC24ZXK300)

10.11868/j.issn.1005-5053.2025.000045

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