水系钠离子电池钛酸亚磷酸盐阳极:进展和展望OA
The NTP Anode for Aqueous Sodium Ion Batteries:Recent Advances and Future Perspectives
水系钠离子电池因其较高的安全性而在水系电池领域备受关注.然而,水基电解液的特性降低了负极材料工作电位以及电化学稳定性,进而阻碍了水系钠离子电池的大规模应用.钛酸亚磷酸盐(NaTi2(PO4)3,NTP)因其出色的电化学性能和可调的结构,被认为是最具实用化前景的用于水系钠离子电池的负极极材料之一.近年来,围绕 NTP 的研究取得了显著进展,但关于其研究现状和未来发展方向的综述仍然缺乏.在此背景下,本文首先介绍了 NTP 的基本特性,并深入分析了其实际应用所面临的挑战.随后,全面概述了提升 NTP电化学性能的改性策略.最后,基于当前的研究状况和实际需求,提出了推动实现水系钠离子电池实际应用的建议和展望.本综述旨在为未来研究提供方向指引,推动从基础材料创新逐步过渡到工业应用,进而加速水系钠离子电池的大规模商业化进程.
Aqueous sodium-ion batteries(ASIBs)have attracted great attention in aqueous batteries due to their merit of high safety.However,the constrained work potential and insufficient chemical stability of anode materials in aqueous electro-lytes hinder the large-scale application of ASIBs.Sodium titanium phosphate,NaTi2(PO4)3(NTP),is considered one of the most promising anode materials for ASIBs due to its excellent electrochemical performance and tunable structure.Recently,great achievements have been made in the development of NTP,however,a comprehensive review of existing studies is still lacking.This article firstly introduces the basic properties of NTP and analyzes the existing challenges.Subsequently,it will provide a comprehensive overview of the key strategies related to the design and modification of NTP materials with optimized electrochemical performance.Finally,based on the current research status and practical needs,suggestions,and future perspectives for advancing NTP in practical applications of ASIBs are presented.This review aims to guide the future research trajectory from basic material innovation to industrial applications,thus promoting the large-scale commercializa-tion of ASIBs.
王明理;苏雪颖;单政翔;杨书哲;郭恒瑞;罗浩;晁栋梁
厦门理工学院材料科学与工程学院,福建 厦门 361024||北京化工大学材料科学与工程学院,北京 100029厦门理工学院材料科学与工程学院,福建 厦门 361024厦门理工学院材料科学与工程学院,福建 厦门 361024北京化工大学材料科学与工程学院,北京 100029厦门理工学院材料科学与工程学院,福建 厦门 361024厦门理工学院材料科学与工程学院,福建 厦门 361024复旦大学化学与材料学院先进材料实验室、水系电池研究中心,上海 20043
水系钠离子电池负极材料钛酸亚磷酸盐储能
Aqueous sodium ion batteryAnode materialNaTi2(PO4)3Energy storage
《电化学（中英文）》 2026 (1)
27-41,15
This work was jointly supported by the Natural Sci-ence Foundation of Fujian Province(No.2024J011210)and the High-Level Talent Start-Up Foundation of Xiamen Institute of Technology(No.YKJ23017R).
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