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Advances in modification approaches for Mg-based hydrogen storage materialsOA

中文摘要

As one of the most promising new energy sources,hydrogen energy is expected to usher in a full-fledged“hydrogen economy”in the 21st century.Compared with traditional high-pressure gaseous and cryogenic liquid hydrogen storage methods,solid-state chemical hydrogen storage shows significant advantages in safety,high efficiency,and cost-effectiveness.Magnesium-based lightweight hydrogen storage materials have attracted widespread attention due to their high gravimetric hydrogen storage density(7.6%)and favorable reversibility.However,their sluggish reaction kinetics and stringent operating conditions(with H2 release temperatures exceeding 350°C and H2 absorption pressures above 4 MPa)pose major challenges for practical applications.Domestic and international researchers have conducted in-depth studies to address these issues,achieving substantial progress in the modification of magnesium-based hydrogen storage alloys.This paper systematically elaborates on major modification techniques such as alloying,nanostructuring,and catalytic material doping,providing a comprehensive analysis of the strengths and limitations of each approach.Furthermore,it offers prospects for the future development of magnesium-based hydrogen storage materials by integrating current theoretical and experimental research findings.

CHENG Shuang;LI Fei;WANG Yuqi;WANG Xiangyi;GUAN Sinan;WANG Yi;WANG Yue;OU Guancheng;XU Ming

School of Chemical Engineering,Northwest University,Xi’an 710127,China Xi’an Key Laboratory of Green Hydrogen Energy Production,Storage&Application Integration Technology,Xi’an 710127,China Shaanxi Key Laboratory of Carbon Neutral Technology,Xi’an 710127,ChinaSchool of Chemical Engineering,Northwest University,Xi’an 710127,China Xi’an Key Laboratory of Green Hydrogen Energy Production,Storage&Application Integration Technology,Xi’an 710127,China Shaanxi Key Laboratory of Carbon Neutral Technology,Xi’an 710127,ChinaSchool of Chemical Engineering,Northwest University,Xi’an 710127,China Xi’an Key Laboratory of Green Hydrogen Energy Production,Storage&Application Integration Technology,Xi’an 710127,China Shaanxi Key Laboratory of Carbon Neutral Technology,Xi’an 710127,ChinaSchool of Chemical Engineering,Northwest University,Xi’an 710127,China Xi’an Key Laboratory of Green Hydrogen Energy Production,Storage&Application Integration Technology,Xi’an 710127,China Shaanxi Key Laboratory of Carbon Neutral Technology,Xi’an 710127,ChinaSchool of Chemical Engineering,Northwest University,Xi’an 710127,China Xi’an Key Laboratory of Green Hydrogen Energy Production,Storage&Application Integration Technology,Xi’an 710127,China Shaanxi Key Laboratory of Carbon Neutral Technology,Xi’an 710127,ChinaSchool of Chemical Engineering,Northwest University,Xi’an 710127,China Xi’an Key Laboratory of Green Hydrogen Energy Production,Storage&Application Integration Technology,Xi’an 710127,China Shaanxi Key Laboratory of Carbon Neutral Technology,Xi’an 710127,ChinaSchool of Chemical Engineering,Northwest University,Xi’an 710127,China Xi’an Key Laboratory of Green Hydrogen Energy Production,Storage&Application Integration Technology,Xi’an 710127,China Shaanxi Key Laboratory of Carbon Neutral Technology,Xi’an 710127,ChinaSchool of Chemical Engineering,Northwest University,Xi’an 710127,China Xi’an Key Laboratory of Green Hydrogen Energy Production,Storage&Application Integration Technology,Xi’an 710127,China Shaanxi Key Laboratory of Carbon Neutral Technology,Xi’an 710127,ChinaXi''an K-Well New Material Co.,Ltd.,Xi’an 710086,China Shaanxi Yefang New Material Co.,Ltd.,Xi’an 712021,China

通用工业技术

magnesium hydridesolid-state hydrogen storagemodificationkineticsthermodynamics

《燃料化学学报(中英文)》 2026 (2)

P.46-63,18

Supported by Design and Performance Study of High-flux Metal Hydride Reactor Based on the Bionic Optimization(2078262)the‘Four-Chain’Integration Project at the Qinchuangyuan Chief Platform(S2025-YF-ZDXM)。

10.1016/S1872-5813(25)60596-2

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