Fluffy LDH/GO 2D membrane for rapid removal of soluble pollutants and enhanced catalytic self-cleaning performanceOA
The rapid expansion of the chemical and pharmaceutical industries has resulted in the introduction of various sources of micropollutants into the environment,posing threats to drinking water quality and public health.Membrane separation technology offers a promising solution with low energy use,high-quality effluent,and operational simplicity.Here,we developed fluffy layered double hydroxides(LDH)/graphene oxide(GO)2D membranes,specifically tannic acid-mediated LDH-GO/GO-TA composite membranes(LG/GT).The integration of GO nanosheets regulated the growth of LDH,enhancing electron transfer and adsorption-driven catalytic performance.This design enabled LDH-GO to activate peroxymonosulfate(PMS)and completely degraded Rhodamine B(RhB)within 10 min.The Gaussian calculation was combined with this finding,which could explain the catalytic self-cleaning in the separation process.The TA-mediated enhancement further increased the RhB rejection of LG/GT-7.5 to 99.23%.Additionally,the needle/sheet structure significantly improved permeance to 358.28 L m^(-2) h^(-1) bar^(-1),surpassing the L/GT-7.5 performance(e.g.338.53 L m^(-2) h^(-1) bar^(-1)),indicating superior pore formation and water mass transfer.The heterostructure between GO and LDH greatly improved cycling stability,with the membrane maintaining a permeance of 282.71 L m^(-2) h^(-1) bar^(-1) and a rejection of 97.97% despite 20 cycles.This work demonstrated the potential of fluffy layered LDH 2D membranes for enhanced wastewater treatment applications.These findings suggested significant potential for practical implementation in industrial wastewater treatment processes,offering a sustainable and efficient solution to water pollution challenges.
Ruilong Zhang;Jun Zhao;Qiangqiang Jia;Jian Ye;Xiaohua Tian;Lulu Wang;Ifunanya R.Akaniro;Prince N.Amaniampong;Jianming Pan;Jiangdong Dai
Institute of Green Chemistry and Chemical Technology,Advanced Chemical Engineering Laboratory of Green Materials and Energy of Jiangsu Province,School of Chemistry and Chemical Engineering,Jiangsu University,Zhenjiang,212013,China The Sino-Forest Applied Research Centre for Pearl River Delta Environment,Department of Biology,Hong Kong Baptist University,Hong Kong SAR,999077,ChinaThe Sino-Forest Applied Research Centre for Pearl River Delta Environment,Department of Biology,Hong Kong Baptist University,Hong Kong SAR,999077,China Institute of Advanced Materials,Hong Kong Baptist University,Hong Kong SAR,999077,ChinaInstitute for Science and Applications of Molecular Ferroelectrics,Key Laboratory of the Ministry of Education for Advanced Catalysis Materials,Zhejiang Normal University,Jinhua,321004,ChinaInstitute of Green Chemistry and Chemical Technology,Advanced Chemical Engineering Laboratory of Green Materials and Energy of Jiangsu Province,School of Chemistry and Chemical Engineering,Jiangsu University,Zhenjiang,212013,China The Sino-Forest Applied Research Centre for Pearl River Delta Environment,Department of Biology,Hong Kong Baptist University,Hong Kong SAR,999077,ChinaInstitute of Green Chemistry and Chemical Technology,Advanced Chemical Engineering Laboratory of Green Materials and Energy of Jiangsu Province,School of Chemistry and Chemical Engineering,Jiangsu University,Zhenjiang,212013,ChinaInstitute of Green Chemistry and Chemical Technology,Advanced Chemical Engineering Laboratory of Green Materials and Energy of Jiangsu Province,School of Chemistry and Chemical Engineering,Jiangsu University,Zhenjiang,212013,ChinaThe Sino-Forest Applied Research Centre for Pearl River Delta Environment,Department of Biology,Hong Kong Baptist University,Hong Kong SAR,999077,ChinaInstitut de Chimie des Milieux et Materiaux de Poitiers,University of Poitiers,CNRS 1 R,UKue Marcel Dore,86073,Poitiers,FranceInstitute of Green Chemistry and Chemical Technology,Advanced Chemical Engineering Laboratory of Green Materials and Energy of Jiangsu Province,School of Chemistry and Chemical Engineering,Jiangsu University,Zhenjiang,212013,ChinaInstitute of Green Chemistry and Chemical Technology,Advanced Chemical Engineering Laboratory of Green Materials and Energy of Jiangsu Province,School of Chemistry and Chemical Engineering,Jiangsu University,Zhenjiang,212013,China
化学化工
LDH layered membraneFluffy 2D membraneCatalytic self-cleaningPMSRemoval of soluble pollutants
《Green Chemical Engineering》 2026 (2)
P.168-179,12
supported by Jiangsu Funding Program for Excellent postdoctoral Talent(2023ZB453 and 2023ZB108)National Natural Science Foundation of China(22306075 and 22108103)Hong Kong Environment and Conservation Fund(2022-127).
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