聚酰亚胺/石墨烯改性复合材料对氢气传感器气敏性能的优化OA
Optimization of Gas Sensitivity Performance of Hydrogen Sensors by Polyimide/Graphene Modified Composites
为了有效优化氢气传感器气敏性能,文章研究聚酰亚胺/氧化石墨烯(PI/GO)改性复合材料对氢气传感器气敏性能的优化效果.以鳞片石墨与硝酸钠等为原料,通过Hummers法制备氧化石墨烯(GO)溶液,将其与聚酰亚胺(PI)混合,设计不同聚四氟乙烯(PTFE)掺入比例,制备PI/GO改性复合材料,将未添加PTFE的复合材料作为对照组,制作氢气传感器;通过智能微分析系统与气敏仪组装测试箱分析不同PTFE掺入比例下PI/GO改性复合材料对氢气传感器气敏性能的优化效果.结果表明:添加PTFE对PI/GO改性复合材料的气敏性能具有明显优化效果.PTFE掺入质量分数为5%时,传感器的气敏响应绝对值达到0.05,灵敏度达到0.5以上,电压变化幅值达到350 mV以上,检出限(LOD)高于7.5 μmol/mol,氢诱导晶格应变率高于1.4%,气敏性能优化效果最佳.
In order to effectively optimize the gas sensing performance of hydrogen sensors,the article studied the optimization effect of polyimide/graphene oxide(PI/GO)modified composites on the gas sensing performance of hydrogen sensors.Using flake graphite and sodium nitrate as the raw materials,graphene oxide(GO)solution was prepared by Hummers method,mixed with polyimide(PI),and different PTFE doping ratios were designed to prepare PI/GO modified composites.The composite without PTFE was used as the control group to fabricate a hydrogen gas sensor.By assembling an intelligent microanalysis system and a gas sensor in a test box,the optimization effect of PI/GO modified composites on the gas sensing performance of hydrogen sensors under different PTFE doping ratios was analyzed.The results show that the addition of PTFE has a significant optimization effect on the gas sensing performance of PI/GO modified composites.When the PTFE doping mass fraction is 5%,the absolute value of the gas sensing response of the sensor reaches 0.05,the sensitivity reaches 0.5 or above,the voltage change amplitude reaches 350 mV or above,the limit of detection(LOD)value is higher than 7.5 μmol/mol,the hydrogen induced lattice strain rate is higher than 1.4%,and the optimization effect of gas sensing performance is the best.
刘馨璐;梁欣
中国石化销售股份有限公司应用技术研究院,天津 300384中国石化销售股份有限公司应用技术研究院,天津 300384
通用工业技术
聚酰亚胺石墨烯复合材料氢气传感器气敏性能
PolyimidegrapheneCompositesHydrogen sensorGas sensing performance
《塑料科技》 2026 (1)
92-96,5
中国石化集团公司科技项目(123072)
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