硫酸亚铁协同胶凝材料固化填埋场市政污泥试验研究OA
Experimental study on solidifying landfilled municipal sludge using ferrous sulfate and cementitious materials
为解决填埋场扩容扩建工程中市政污泥含水率高、强度低的问题,提出硫酸亚铁协同胶凝材料(石灰、粉煤灰和水泥)原位固化填埋污泥的方法,并采用响应面法对该协同固化方法的药剂掺量进行优化.以养护28 d后固化污泥的含水率、无侧限抗压强度(UCS)作为评价指标,开展单因素试验,探究硫酸亚铁及各胶凝材料在污泥固化过程中的作用;借助响应面法分析硫酸亚铁以及各胶凝材料之间的交互作用,进而优化药剂材料的掺量.结果表明:硫酸亚铁与胶凝材料均能降低固化污泥的含水率,其中,石灰、水泥的降低效果更显著;固化污泥的UCS随硫酸亚铁、水泥掺量的增加而增大,随石灰掺量先增大后减小,但基本不受粉煤灰掺量的影响;响应面法建立的二次多项式模型能较准确地预测固化污泥的含水率和UCS,预测值与试验值相对误差小于20%;在设置的约束条件下,推荐优化方案R7(硫酸亚铁8%,石灰6%,粉煤灰10%,水泥11%),该方案下固化污泥的含水率由360.3%降低至131.5%,UCS由0 kPa提升至317.0 kPa,满足填埋处置规定以及机械进场要求.
In order to address the issues of elevated water content and diminished strength of municipal sludge in the landfills,a synergistic method using ferrous sulfate and cementitious materials(such as lime,fly ash,and cement)was proposed for the in-situ solidification of landfilled sludge,with its reagent dosage further optimized by the response surface method(RSM).In this study,the water content and unconfined compressive strength(UCS)of the solidified sludge after 28 days of curing were selected as evaluation indexes.Initially,a single factor test was conducted to explore the roles of ferrous sulfate and cementitious materials in the sludge solidification process,followed by the analysis of interactions between ferrous sulfate and cementitious materials using RSM to optimize the material dosages.The results showed that both ferrous sulfate and cementitious materials could reduce the water content of the solidified sludge,with lime and cement exhibiting more significant reduction effects;the UCS of the solidified sludge increased with increasing ferrous sulfate and cement dosages,first increased and then decreased with lime dosage,and remained essentially unchanged with fly ash dosage;the quadratic polynomial model derived from RSM could accurately predict the water content and UCS of the solidified sludge,and verification indicated that the relative error between the predicted and experimental values was less than 20%;under the constraints set in this study,the water content of the solidified sludge in the recommended solution R7(ferrous sulfate 8%,lime 6%,fly ash 10%,and cement 11%)decreased from 360.3%to 131.5%,while the UCS increased from 0 to 317.0 kPa.The aforementioned results met the requirements for landfill disposal and mechanical access.
郭晓静;黄志亮;陈辉;何肖;蒲诃夫;袁满;曹剑峰
北京泾渭环境科技有限公司,北京 100020北京泾渭环境科技有限公司,北京 100020北京泾渭环境科技有限公司,北京 100020华中科技大学 土木与水利工程学院,武汉 430074华中科技大学 土木与水利工程学院,武汉 430074华中科技大学 土木与水利工程学院,武汉 430074华中科技大学 土木与水利工程学院,武汉 430074
资源环境
填埋污泥固化协同硫酸亚铁胶凝材料
landfilled sludgesolidificationsynergismferrous sulfatecementitious materials
《土木与环境工程学报(中英文)》 2026 (1)
210-220,11
国家重点研发计划(2019YFC1806003) The National Key R&D Program of China(No.2019YFC1806003)
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