面向智能纺织的钙钛矿交流电致发光纤维OA
Perovskite AC Electroluminescent Fibers for Smart Textiles
针对智能纺织品对电致发光器件的迫切需求,本研究提出一种新型钙钛矿基交流电致发光(ACEL)纤维解决方案.聚焦钙钛矿量子点虽具有优异色纯度却无法直接响应交流电的特性,通过构建CsPbBr3/ZnS/TPU复合体系实现了技术突破:采用湿法纺丝连续制备同轴纤维,借助ZnS与CsPbBr3间的Förster共振能量转移机制,将交流电能有效地转化为光辐射,并依托热塑性聚氨酯(TPU)实现柔性封装.所获纤维在交流电场下呈现23~37 nm窄带绿色发光(CIE坐标0.213 8,0.642 5),经500次机械弯折仍能保持82%以上初始亮度,具备优异的图案编织构筑能力.该研究攻克了可穿戴光电器件中材料光电响应机制与柔性基底的协同适配难题,为智能纺织品开发高色域柔性光源、动态交互界面等核心组件提供了可产业化的技术路径.
In response to the urgent demand for electroluminescent devices in smart textiles,this study proposes a novel perovskite-based alternating current electroluminescence(ACEL)fiber solution.Focusing on the characteris-tic that perovskite quantum dots,despite their excellent color purity,cannot directly respond to alternating current,a technical breakthrough is achieved by constructing a CsPbBr3/ZnS/TPU composite system.Wet spinning is used to continuously prepare coaxial fibers,and the Förster energy resonance transfer mechanism between ZnS and CsPbBr3 is utilized to effectively convert alternating current energy into light radiation,with flexible encapsulation achieved through thermoplastic polyurethane(TPU).The obtained fibers exhibit narrow-band pure green emission(CIE coor-dinates 0.213 8,0.642 5)under alternating current fields,maintaining over 82%of their initial brightness after 500 mechanical bends,and possess excellent pattern weaving construction capabilities.This research overcomes the challenge of the coordinated adaptation of the material's photoelectric response mechanism and flexible substrate in wearable optoelectronic devices,providing an industrializable technical path for the development of high-color-do-main flexible light sources and dynamic interactive interfaces in smart textiles.
王海龙;林隆辉;刘光颖;赵强;游超瑜
青岛大学纺织服装学院,山东青岛 266071厦门医学院药学院,福建厦门 361000青岛大学纺织服装学院,山东青岛 266071塔里木大学纺织服装学院,新疆塔里木 843300青岛大学纺织服装学院,山东青岛 266071||塔里木大学纺织服装学院,新疆塔里木 843300
数理科学
钙钛矿交流电致发光同轴湿法纺丝能量共振转移可编织图案化
perovskiteAC electroluminescencecoaxial wet spinningenergy resonance transferweavable patterning
《发光学报》 2026 (1)
45-55,11
胡杨英才-引进人才科研启动金(博士)项目(TDZKBS202655)青岛博士后创新项目(QDBSH20220202210)兵团财政科技计划项目(2022DB011)师市科技攻关计划项目(2024GX02)Supported by Populus Euphratica Talent Program-Research Start-up Fund for Introduced Talents(Ph.D.)Project(TDZKBS202655)Qingdao Postdoctoral Innovation Project(QDBSH20220202210)Xinjiang Production and Construction Corps Financial Sci-ence and Technology Plan Project(2022DB011)Division and City Science and Technology Research Project(2024GX02)
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