玉米秸秆活性炭的制备及性能研究OA
Preparation and Performance Evaluation of Activated Carbon Derived from Corn Stalks
以玉米秸秆这种农业生物质废弃物为原料开展活性炭制备工作,制备微孔结构丰富的活性炭产品,采用高温碳化和水蒸气或者二氧化碳活化方法,在氮气的保护下,在此温度区间内,既能保证活化反应充分进行,又可避免过度碳化导致活性炭性能下降.活化时间通常控制在 1~3h,时间过短活化不充分,时间过长则可能破坏孔隙结构.根据不同应用需求进行成型处理.若用于气相吸附,可制成颗粒状活性炭,通过挤压成型或圆盘造粒等方法,将粗制活性炭与适量黏结剂(如羧甲基纤维素钠)混合后制成一定粒径(如 2~4mm)的颗粒;若用于液相吸附或催化载体,可制成粉末状活性炭,将粗制活性炭进一步研磨至合适粒度(如 0.077~0.054 mm(200~300 目)).用秸秆制备的活性炭在性能方面能达到竹炭的水平,可以用作后期的研究和产品制备.
This study uses corn stover,an agricultural biomass waste,as raw material to prepare activated carbon products with rich pore struc-ture.The method adopts high-temperature carbonization and steam or carbon dioxide activation.Under the protection of nitrogen gas,within this temperature range,the activation reaction can be fully carried out and the performance of activated carbon can be avoided from deteriorating due to excessive carbonization.The activation time is usually controlled within 1~3 hours.If the reaction time is too short,the activation may not be sufficient,and if the reaction time is too long,it may damage the pore structure.Molding processing is carried out according to different ap-plication requirements.If used for gas-phase adsorption,it can be made into granular activated carbon,which can be mixed with an appropriate amount of binder(sodium carboxymethyl cellulose)through extrusion molding or disc granulation methods to produce particles with a certain particle size(2~4 mm);If used as a liquid-phase adsorption or catalytic carrier,it can be made into powdered activated carbon,and the crude activated carbon can be further ground to a suitable particle size(0.077~0.054 mm(200~300 mesh)).Activated carbon prepared from straw can reach the level of bamboo charcoal in terms of performance and can be used for later research and product preparation.
张秀丽;余白云;刘心怡;程鹏;王延明
青岛工程职业学院,山东 青岛 266111青岛工程职业学院,山东 青岛 266111青岛工程职业学院,山东 青岛 266111青岛工程职业学院,山东 青岛 266111青岛工程职业学院,山东 青岛 266111
化学化工
玉米秸秆活性炭性能测试
Corn StrawActivated CarbonPerformance Testing
《云南化工》 2026 (1)
38-41,4
山东省职业教育教学改革研究项目(2024362)2024年度山东省教育教学研究课题(2024JXY535).
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