不同形貌氧化锌微米晶体的水热法控制合成OA
Controlled Synthesis of Zinc Oxide Microcrystals with Distinct Morphologies via Hydrothermal Method
采用水热合成-活化刻蚀联用法合成了6种不同形貌(棒状、管状、螺丝状、棒状花簇、管状花簇和螺丝花簇)的氧化锌粒子.通过调节水热反应参数实现了对氧化锌从棒状分散形态到聚集簇的可控合成;并利用氧化锌晶面的稳定性差异,通过定制化后刻蚀法,有效控制氧化锌形貌从棒状到中空管状和螺丝棒状的演变.光电化学测试结果表明,氧化锌的差异性形貌特征直接影响其光电化学性质.本文工作对合成特定形貌的氧化锌来应对不同应用场景的定制化需求具有参考价值.
A method of hydrothermal synthesis coupled with activation etching was employed to synthesize zinc oxide(ZnO)particles with six distinct morphologies:rod,tube,screw,rod-flower,tube-flower,and screw-flower.The controlled synthesis of ZnO from dispersed rods to aggregated rod-flower clusters was achieved by adjusting the parameters of the hydrothermal reaction.Moreover,by exploiting the differences in the stability of various crystal faces,a customized post-etching method was used to effectively control the morphological evolution of ZnO from rod-like structure to tubular and screw-like structures.The results of photoelectrochemical test indicated that the distinct morphology of ZnO played a significant role in its photoelectrochemical property.These findings offer valuable insights into the synthesis of ZnO with specific morphologies to tailor its properties for particular application.
陈杨;王芙香;仇一朵;黄宇桐;赵晓君;潘勤鹤
海南大学物理与光电工程学院,海口 570228||海南大学化学化工学院,海口 570228海南大学物理与光电工程学院,海口 570228海南大学化学化工学院,海口 570228海南大学化学化工学院,海口 570228海南大学化学化工学院,海口 570228海南大学化学化工学院,海口 570228
化学化工
氧化锌晶体形貌控制合成光电化学性质
Zinc oxideCrystal morphologyControlled synthesisPhotoelectrochemical property
《高等学校化学学报》 2026 (2)
18-26,9
国家自然科学基金(批准号:22461016,22361017)、海南省自然科学基金(批准号:524MS027)和海南省院士创新平台科研项目(批准号:YSPTZX202321)资助. Supported by the National Natural Science Foundation of China(Nos.22461016,22361017),the Hainan Provincial Natural Science Foundation,China(No.524MS027)and the Specific Research Fund of the Innovation Platform for Academicians of Hainan Province,China(No.YSPTZX202321).
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