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石化行业VOCs排放风险评估研究进展OA

Research Progress on Risk Assessment of VOCs Emissions in the Petrochemical Industry

中文摘要英文摘要

随着石化产业的快速发展,与石油炼制和化学工艺过程相关的环境与人类健康问题备受关注,使得石化行业挥发性有机物(VOCs)风险评估成为当前研究热点.但目前缺乏对现有研究的系统性梳理,导致难以从整体上把握VOCs风险的共性与规律.因此,基于已有研究中的数据,综合分析了石化行业VOCs对臭氧及健康的影响.研究结果表明,在臭氧风险方面,烯烃是臭氧生成潜势(OFP)最主要的贡献者,其中丙烯、间/对-二甲苯、3-甲基庚烷和反式-2-丁烯为关键活性物种.OFP 呈现季节性差异,夏季因光化学反应加剧而达到峰值;同时,其评估结果也显著受计算方法影响,存在不确定性.在健康风险方面,苯和1,3-丁二烯等物质在VOCs管控体系下,其对人群健康的影响处于可接受水平.未来,应重点加强对高活性烯烃和芳香烃的泄漏控制,对烷烃等低活性组分实施浓度阈值管理.同时选择合适的OFP计算方法,并将季节变化、气象条件与职业暴露等因素纳入考量因素,从而提升VOCs精准监测与管控能力.

With the rapid development of the petrochemical industry,environmental and human health is-sues related to petroleum refining and chemical processes have garnered significant attention,making the risk assessment of volatile organic compounds(VOCs)in the petrochemical industry a current research focus.How-ever,the lack of a systematic review of existing research makes it difficult to grasp the commonalities and pat-terns of VOCs risks as a whole.Therefore,based on the data from existing research,a comprehensive analysis was conducted on the impact of VOCs in the petrochemical industry on ozone and health.The research results showed that in terms of ozone generation risk,olefins were the primary contributors to the ozone generation po-tential(OFP),with propylene,m/p-xylene,3-methylheptane,and trans-2-butene as key active species.OFP exhibited seasonal variation,peaking in summer due to intensified photochemical reactions.Meanwhile,its as-sessment results were significantly influenced by the calculation method,introducing uncertainty.In terms of health risks,substances such as benzene and 1,3-butadiene have an acceptable impact on human health under the VOCs control system.In the future,efforts should prioritize enhancing the leakage control of highly active alkenes and aromatics,while implementing concentration threshold management for low-active components such as alkanes.Selecting appropriate OFP calculation methods and incorporating seasonal variations,meteorological conditions,and occupational exposure factors will enhance the precision of VOCs monitoring and control capa-bilities.

彭金蝉;李晓;郭一蓉;王志军;肖安山;冯云霞;高松

化学品安全全国重点实验室,山东 青岛 266104||中石化安全工程研究院有限公司,山东 青岛 266104中国石化青岛石油化工有限责任公司,山东 青岛 266043化学品安全全国重点实验室,山东 青岛 266104||中石化安全工程研究院有限公司,山东 青岛 266104中国石化青岛石油化工有限责任公司,山东 青岛 266043化学品安全全国重点实验室,山东 青岛 266104||中石化安全工程研究院有限公司,山东 青岛 266104化学品安全全国重点实验室,山东 青岛 266104||中石化安全工程研究院有限公司,山东 青岛 266104上海大学环境与化学工程学院,上海 200444

资源环境

挥发性有机物风险管控石化园区健康风险评估臭氧生成潜势排放特征

volatile organic compoundsrisk controlpetrochemical parkhealth risk assessmentozone formation potentialemission characteristics

《安全、健康和环境》 2026 (1)

1-10,10

中国石化科技部项目(324005),石化企业典型异味源臭气浓度定量表征技术及装备研究.

10.3969/j.issn.1672-7932.2026.01.001

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