首页|期刊导航|四川大学学报(自然科学版)|燃料温度对正癸烷裂解气扩散火焰推举影响研究

燃料温度对正癸烷裂解气扩散火焰推举影响研究OA

Study on the influence of fuel temperature on the lift-off of diffusion flame of n-decane pyrolysis gas

中文摘要英文摘要

喷气燃料高温裂解产物的燃烧特性直接关系到超燃冲压发动机的燃烧效率与运行安全性,而火焰推举现象作为扩散燃烧中的关键特征,对燃烧稳定性及污染物排放具有重要影响.正癸烷是喷气燃料的典型替代组分之一,本文利用耦联电加热流动管反应器与热伴流射流扩散燃烧器,对正癸烷在温度500~850℃的热裂解产物喷注燃烧特性进行了实验与理论分析研究.通过模拟计算了单组分乙烯与双组分正癸烷/乙烯的非反应混合过程.计算结果表明,在非反应的热空气与裂解气混合过程中,燃料温度上升带来的显焓提升对局部当量比的影响,远弱于其引发的裂解反应程度加剧对局部当量比的影响,后者是导致其局部当量比分布变化的主导因素.射流扩散火焰观测结果表明,随着燃料温度的升高,火焰的推举高度单调递减,对应滞燃时间均逐渐缩短.基于正癸烷及乙烯的燃烧反应机理计算的零维点火延迟时间,远大于实验中燃料接触空气后的滞燃时间,因此用稳定物种替代热裂解态燃料组成可能严重低估其反应活性.本研究为阐明高温燃料裂解-燃烧耦合过程的内在规律提供了实验支撑,也为发动机燃烧室的优化设计提供了理论依据.

The combustion characteristics of jet fuel high-temperature pyrolysis products are directly related to the combustion efficiency and operational safety of scramjet engines.The flame lift-off phenomenon,as a key feature in diffusion combustion,significantly impacts combustion stability and pollutant emissions.As a typical surrogate component of jet fuel,n-decane is studied in this paper through experimental and theoretical analysis,focusing on the combustion characteristics of the thermal cracking products at temperatures ranging from 500℃to 850℃by coupling an electric heating flow tube reactor and a jet-in-hot-coflow burner.The non-reactive mixing process of single-component ethylene and two-component n-decane/ethylene was studied using numerical simulations.The calculation results show that,with increasing fuel temperature,the en-hanced pyrolysis reaction—rather than the rise in sensible enthalpy—governs the change in the local equiva-lence ratio distribution.The observation results of jet-in-hot-coflow flames indicate that as the fuel tempera-ture increases,the lift-off height of the flame monotonically decreases,and the corresponding delay time of the premixed combustion gradually shortens.Furthermore,the zero-dimensional ignition delay time calcu-lated based on the combustion reaction mechanism of n-decane and ethylene is much longer than the delay time of ignition after fuel-air contact in the experiment.Therefore,using stable species to replace the compo-sition of the high-temperature pyrolysis fuel may seriously underestimate it reactivity.This study provides ex-perimental support for clarifying the inherent mechanisms governing the coupled process of high-temperature fuel pyrolysis and combustion,and also offers a theoretical basis for the optimal design of engine combustors.

赖重华;赵鸿海;黄林远;黄胜

四川大学化学工程学院,成都 610065四川大学化学工程学院,成都 610065四川大学化学工程学院,成都 610065四川大学化学工程学院,成都 610065

化学化工

裂解气正癸烷热伴流火焰火焰推举主动冷却

pyrolysis gasn-decanejet-in-hot-coflow flameflame lift-offactive cooling

《四川大学学报(自然科学版)》 2026 (1)

168-174,7

国家自然科学基金(T2441001)

10.19907/j.0490-6756.250109

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