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二硫化钼/多孔氮化碳复合材料的制备及其结构表征OA

Preparation and structural characterization of molybdenum disulfide/porous carbon nitride composites

中文摘要英文摘要

随着氢能产业的发展,对电化学制氢催化剂的研究愈发深入.二硫化钼(MoS2)因其优异的电催化析氢反应(HER)活性和经济性而受到广泛关注,文章采用构建异质结的方法来提高其催化性能.采用MoS2 与不同质量的多孔氮化碳(pg-C3N4)相复合以改善MoS2 的电子结构,提高其催化HER的能力并探究最佳的p-CN复合质量.实验结果表明,复合 40 mg的pg-C3N4 后,复合材料具有最好的导电性,产氢 2h后,与MoS2 相比,复合材料可提高产氢量超过 10%.研究结果为低成本制氢催化剂的制备提供了新思路.

With the burgeoning development of the hydrogen energy industry,research endeavors focused on electrochemical hydrogen evolution catalysts have intensified significantly.Molybdenum disulfide(MoS2)has garnered substantial attention owing to its remarkable electrocatalytic activity toward the hydrogen evolution reaction(HER)and inherent cost-effectiveness.In this study,a heterojunction engineering strategy was adopted to further optimize its catalytic performance.Specifically,MoS2 was hybridized with varying quantities of porous graphitic carbon nitride(pg-C3N4)to modulate the electronic structure of MoS2,thereby enhancing its HER kinetics and determining the optimal loading mass of pg-C3N4.Experimental results reveal that the composite incorporating 40 mg of pg-C3N4 exhibits superior electrical conductivity.Furthermore,chronopotentiometry tests conducted over 2 hours duration demonstrated that the hydrogen yield of the composite exceeded that of pristine MoS2 by more than 10%.Collectively,these findings offer novel insights into the rational design of low-cost electrocatalysts for hydrogen production.

罗一飞;裴占江;宋泽璟;刘杰;于亦飞;刘广拓;史风梅;王粟;李鹏飞;宋锦东

黑龙江省黑土保护利用研究院,黑龙江 哈尔滨 150086黑龙江省秸秆能源化重点实验室,黑龙江 哈尔滨 150086黑龙江省黑土保护利用研究院,黑龙江 哈尔滨 150086黑龙江省秸秆能源化重点实验室,黑龙江 哈尔滨 150086中国石油大学(北京)新能源与材料学院,北京 102249黑龙江省黑土保护利用研究院,黑龙江 哈尔滨 150086黑龙江省秸秆能源化重点实验室,黑龙江 哈尔滨 150086黑龙江大学 建筑工程学院,黑龙江 哈尔滨 150080东北农业大学 文理学院,黑龙江 哈尔滨 150030黑龙江省黑土保护利用研究院,黑龙江 哈尔滨 150086

能源科技

制氢催化剂多孔氮化碳二硫化钼构建异质结析氢反应

hydrogen production catalystporous carbon nitridemolybdenum disulfidebuilding heterojunctionshydrogen evolution reaction

《可再生能源》 2026 (1)

17-24,8

黑龙江省揭榜挂帅项目(2022ZXJ05C02-03)黑龙江省农业科学院"农业科技创新跨越工程"专项项目(CX22JQ01)黑龙江生猪现代农业产业技术协同创新推广体系项目.

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