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无烟煤煤矸石基础燃烧特性研究OA

Study on the combustion characteristics of anthracite coal gangue

中文摘要英文摘要

天地王坡煤矿生产无烟煤煤矸石,为将煤矸石焚烧处置,亟需研究基础燃烧特性.选取大块矸石和碎末矸石进行研究,无烟煤煤泥作为对比.研究结果表明:大块矸石和煤泥热值较高,超过10.3 MJ/kg,碎末矸石的热值极低;煤灰中SiO2和Al2O3之和超过90%,软化温度大于1 500℃;大块矸石和煤泥的着火指数(Td)、着火稳燃特性(Rw)和燃尽特性(Rj)相近,属于难以着火和燃尽的固体物料;对大块矸石和煤泥进行TG和DGT分析,大块矸石着火和燃尽温度分别为534℃和617℃,煤泥的着火温度和燃尽温度分别为 430℃和 500℃.采用Freeman Carroll法计算煤矸石的动力学参数,得到煤矸石挥发分热解反应级数为 0.688,表观活化能为119 kJ/mol,指前因子为 0.34×1011;煤矸石焦炭燃烧反应级数为 1.87,表观活化能为 189 kJ/mol,指前因子为1.56×1013.

Tiandi Wangpo coal mine produces a large amount of anthracite coal gangue.In order to achieve the goal of resource utilization of coal gangue,it is urgent to study its basic combustion characteristics.Large-sized gangue and fine gangue were selected as the research objects and anthracite coal slime was used as the comparison object.The research results show that the calorific value of large-sized gangue and coal slime is relatively high,exceeding 10.3 MJ/kg.While the calorific value of fine gangue is extremely low.The sum of SiO2 and Al2O3 in the coal ash of the three samples is over 90%and the ash melting point is greater than 1 500℃.The ignition index(Td),stable combustion characteristics(Rw)and burnout characteristics(Rj)of the large-sized gangue and coal slime are simi-lar,both belonging to the category of solid fuels that are difficult to ignite and burn out..TG and DTG analysis of large-sized gangue and coal slime show that the ignition and burnout temperature of the large-sized gangue is 534℃and 617℃respectively.While the ignition and burnout temperature of coal slime is 430℃and 500℃respectively.The kinetic parameter of coal gangue is calculated by the Freeman Carroll method.The result shows that the reaction order of the volatile pyrolysis of coal gangue is 0.688 and the activation energy is 119 kJ/mol.The pre-exponential factor of the pyrolysis reaction is 0.34×1011.As to the char of coal gangue,the reaction order is 1.87,the activa-tion energy is 189 kJ/mol and the pre-exponential factor is 1.56×1013.

马强;陈隆;韩崇刚;孙宁龙

山西天地王坡煤业有限公司 山西 晋城 048000煤炭科学研究总院 北京 100013北京天地融创科技股份有限公司 北京 100013北京天地融创科技股份有限公司 北京 100013

化学化工

煤矸石煤泥燃烧特性动力学参数

coal ganguecoal slimecombustion characteristicskinetic parameters

《煤质技术》 2026 (1)

54-59,6

山西天地王坡煤业有限公司企业课题煤矸石焚烧处置关键技术与综合利用方案研究资助(12017)

10.3969/j.issn.1007-7677.2026.01.07

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