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熔融结晶分离同分异构体的研究及进展OA

Research and progress on separation of isomers by melt crystallization

中文摘要英文摘要

熔融结晶是1 种基于组分熔点差异和固液相平衡的分离技术,通过控制温度变化使目标组分从熔体中结晶析出,从而实现分离纯化.与传统的分离方法相比,熔融结晶具有能耗低、产品纯度高、分离效率高、操作条件温和等优点,尤其适用于分离沸点相近、热敏易变质、难以通过蒸馏分离的同分异构体.近年来,随着对熔融结晶研究深入理解和工艺的不断优化,该技术在分离同分异构体方面取得显著进展.笔者简述熔融结晶的基本原理和特点,介绍熔融结晶的不同技术类型,重点讨论熔融结晶技术在各种同分异构体分离中的研究,突出该技术在石油化工、煤化工、精细化工、聚合物单体提纯等领域的应用前景.最后,指出熔融结晶技术面临的挑战和未来的发展方向,旨在为熔融结晶在同分异构体分离领域的进一步研究和应用提供参考.

Melt crystallization is a separation technology based on the differences in melting points of components and solid-liquid phase equilibrium.By controlling temperature changes,the target component crystallizes and precipitates from the melt,thereby achieving separation and purification.Compared with traditional separation methods,melt crystallization has the advantages of low energy consumption,high product purity,high separation efficiency,and mild operating conditions.It is particularly suitable for separating isomers with similar boiling points,thermal suscep-tibility to deterioration,and difficult to separate by distillation.In recent years,with a deeper understanding of melt crystallization research and continuous optimization of processes,this technology has made significant progress in sep-arating isomers.This article briefly describes the basic principles and characteristics of melt crystallization,intro-duces different types of melt crystallization technologies,and focuses on the research of melt crystallization technology in the separation of various isomers.It highlights the application prospects of this technology in the fields of petro-chemical,coal chemical,fine chemical,and polymer monomer purification.Finally,the challenges and future de-velopment directions of melt crystallization technology aim to provide a reference for further research and application of melt crystallization in the field of isomer separation.

李恒

煤炭科学技术研究院有限公司,北京 100013;国家能源煤炭高效利用与节能减排技术装备重点实验室,北京 100013;煤基节能环保炭材料北京市重点实验室,北京 100013;中国煤科低碳技术研究院,北京 100013

化学化工

熔融结晶同分异构体分离纯化分离技术应用前景

melt crystallizationisomersisolation and purificationseparation technologyapplication prospects

《煤质技术》 2026 (1)

28-36,9

煤炭科学技术研究院有限公司科技发展基金资助项目(2024ZDI-04)中国煤炭科工集团有限公司科技创新创业资金资助项目(2023-2-TD-ZD008)

10.3969/j.issn.1007-7677.2026.01.04

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