饮用水中全氟和多氟烷基物质的污染特征及管控OA
Characteristics and Control of Per-and Polyfluoroalkyl Substances Pollution in Drinking Water
[目的]全氟和多氟烷基物质(PFASs)被广泛应用于各种工业产品和日常消费品中,已成为受到广泛关注的持久性有机污染物.环境水体中已普遍检出PFASs,人体通过饮水摄入是PFASs主要暴露途径之一,开展饮用水中PFASs赋存特征研究对于PFASs的防控至关重要.[方法]本文论述了 PFASs的种类,除了包含全氟烷基羧酸(PFCAs)和全氟烷基磺酸(PFSAs)两大类传统PFASs外,还包含了新型PFASs的典型类别,并从直接排放和间接迁移两方面,对饮用水中PFASs的污染来源进行分析.对比了国内外饮用水中PFASs的污染种类及分布特征,列举了各国在饮用水相关标准中对PFASs的管控.[结果]在饮用水中检测到的新型PFASs的占比虽然低于PFCAs和PFSAs,但检测到的种类日益增多,六氟环氧丙烷二聚酸(HFPO-DA)、六氟环氧丙烷三聚酸(HFPO-TA)、6∶2氟调磺酸(FTS)、6∶2氯代多氟醚磺酸(Cl-PFESA)等新型PFASs检出频繁.[结论]国内外饮用水标准中对PFASs限值的规定趋于严格化,低至纳克每升水平.低浓度限值的实施,使部分地区饮用水中PFASs的浓度超出标准规定的限值,这对饮用水中PFASs去除提出更高要求,需要污染源管控、饮用水处理技术改进以及健康风险评估等多个环节协同作用,以保障公众饮水健康.
[Objective]Per-and polyfluoroalkyl substances(PFASs)are extensively utilized in industrial products and daily consumer goods,emerging as persistent organic pollutants of global concern.Their frequent detection in environmental water bodies poses significant risks,as ingestion through drinking water constitutes a primary exposure pathway for humans.Investigating the occurrence characteristics of PFASs in drinking water is critical for pollution prevention and control.[Methods]This paper systematically reviews the classification of PFASs,including traditional PFASs such as perfluorocarboxylic acids(PFCAs)and perfluorosulfonic acids(PFSAs),as well as emerging categories of novel PFASs.Pollution sources in drinking water are examined through dual lenses of direct emission and indirect migration pathways.A comparative analysis of PFASs profiles and distribution patterns in drinking water systems is conducted at home and abroad,accompanied by an inventory of existing regulatory standards for PFASs.[Results]While novel PFASs constitute a smaller fraction of detected contaminants compared to PFCAs and PFSAs,their diversity is rising steadily.Emerging compounds such as hexafluoropropylene oxide dimer acid(HFPO-DA),hexafluoropropylene oxide trimer acid(HFPO-TA),6∶2 fluorotelomer sulfonic acid(FTS),and 6∶2 chlorinated polyfluorinated ether sulfonic acid(Cl-PFESA)are increasingly reported.[Conclusion]Limited values for PFASs in drinking water standards at home and abroad are becoming increasingly strict,down to the level of nanograms per liter.Implementation of these stringent limits have exposed PFASs contamination exceeding permissible concentrations in certain regions,challenging water treatment systems.Multi-faceted approachs including pollution source control,drinking water treatment technologies improvement,and health risk assessments are needed to guarantee public drinking water safety.
陈永艳;吕佳;张岚;叶必雄;王媛园;苏钜昌
中国疾病预防控制中心环境与健康相关产品安全所,中国疾病预防控制中心环境与人群健康重点实验室,北京 100050中国疾病预防控制中心环境与健康相关产品安全所,中国疾病预防控制中心环境与人群健康重点实验室,北京 100050中国疾病预防控制中心环境与健康相关产品安全所,中国疾病预防控制中心环境与人群健康重点实验室,北京 100050中国疾病预防控制中心环境与健康相关产品安全所,中国疾病预防控制中心环境与人群健康重点实验室,北京 100050中国疾病预防控制中心环境与健康相关产品安全所,中国疾病预防控制中心环境与人群健康重点实验室,北京 100050安利<中国>日用品有限公司,广东 广州 510613
建筑与水利
全氟和多氟烷基物质饮用水污染特征污染管控污染来源
per-and polyfluoroalkyl substances(PFASs)drinking waterpollution characteristicpollution controlpollution source
《净水技术》 2026 (1)
1-9,92,10
国家重点研发计划(2021YFC3200804)
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