多孔介质复合相变材料孔隙结构优化与传热强化研究OA
Optimization of pore structure and heat transfer enhancement in porous composite phase change materials
本工作旨在系统研究梯级多孔骨架结构对复合相变材料(C-PCMs)传热与储热性能的优化机理,重点探究孔结构中孔径分布、孔径梯度与孔隙率分布对相变过程的影响.通过构建孔隙尺度下的多孔介质物理模型,采用焓-孔隙度法进行数值模拟,分析不同孔隙结构下相变材料(PCMs)的熔化行为、液相流动及储热特性.研究结果表明,孔径分布在均匀孔隙率条件下对熔化过程具有显著影响.其中大孔径布置于热源端、小孔径布置于远端的分布方式能够最大程度发挥大小孔的自然对流与导热协同作用,熔化时间缩短16.8%.此外,横向连通的孔径梯度结构能够诱发局部微对流效应,尤其在大孔与小孔交界处,液相前沿弯曲更加明显,并在熔化后期使平均储热效率最高提升17.5%.相比之下,孔隙率分布对熔化过程的影响相对有限:前端低孔隙率比例增加虽可略微缩短熔化时间,但会导致总储热量和平均储热功率分别下降1.6%和1.7%.综上,本研究揭示了孔隙结构对C-PCMs熔化传热过程的作用机理,为设计孔径分布、梯度及孔隙率以实现高效储能的理论指导与方法依据,对多孔介质C-PCMs的优化设计具有重要参考价值.
This study systematically investigates the optimization mechanisms of graded porous skeleton structures on the heat transfer and thermal energy storage performance of composite phase change materials(C-PCMs).The effects of pore size distribution,pore size gradient,and porosity distribution on the phase change process are examined.A pore-scale physical model of porous media is constructed,and the enthalpy-porosity method is employed for numerical simulations to analyze the melting behavior,liquid-phase flow,and thermal storage characteristics of phase change materials(PCMs)with different pore structures.The results show that pore size distribution markedly influences the melting process under uniform porosity conditions.Arranging large pores near the heat source and small pores at the far end maximizes the synergistic effects of natural convection and conduction within large and small pores,reducing the melting time by 16.8%.Moreover,transverse gradient pore structures induce localized microconvection,particularly at the interfaces between large and small pores,where the liquid front exhibits pronounced curvature,enhancing average thermal storage efficiency by up to 17.5%during the later melting stage.In contrast,the impact of porosity distribution is relatively minor:although increasing the proportion of low-porosity regions near the heat source slightly shortens melting time,it decreases total heat storage and average storage power by up to 1.6%and 1.7%,respectively.Overall,this work elucidates the influence of pore structure on the melting heat transfer of C-PCMs and provides theoretical guidance for achieving efficient energy storage through rational design of pore size distribution,gradient structures,and porosity,offering valuable insights for optimizing inorganic porous C-PCMs.
陶梦晓;蔡锦龙;姜峰;凌祥
南京工业大学机械与动力工程学院,江苏 南京 211816南京工业大学机械与动力工程学院,江苏 南京 211816南京工业大学机械与动力工程学院,江苏 南京 211816南京工业大学机械与动力工程学院,江苏 南京 211816
能源科技
复合相变材料多孔介质梯度孔骨架相变储热传热强化
composite phase change materialsporous mediagradient pore skeletonphase change thermal storageheat transfer enhancement
《储能科学与技术》 2026 (1)
38-48,11
国家自然科学基金项目(52204420),江苏省研究生创新实践项目(SJCX25_0604).
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