首页|期刊导航|铸造|白云石煅烧分解产物组成及活性转变研究

白云石煅烧分解产物组成及活性转变研究OA

Study on Composition and Activity Transformation of Dolomite Calcination Decomposition Products

中文摘要英文摘要

通过煅烧白云石原矿制备其在不同温度下的分解产物,采用TG-DTA、XRD、FTIR和SEM对白云石煅烧分解产物进行表征,研究了白云石分解过程中产物组成及活性的变化,探究了白云石在煅烧过程中晶体结构的变化.结果表明:在10℃/min煅烧条件下,白云石分解分为MgCO3分解、CaCO3少量分解和CaCO3大量分解三个阶段,800℃左右白云石开始分解,其分解产物为MgO和CaCO3,煅烧产物中MgO的活性含量随煅烧温度的升高而增加,其活性含量可达15.78%;CaCO3少量分解阶段,分解产物为MgO、CaCO3和少量的CaO,分解产物的活性含量为20.0%~23.78%;CaCO3大量分解后,分解产物中活性含量急剧升高,其活性氧化物含量大于50%,最后白云石逐渐完全分解为CaO和MgO.

The thermal decomposition products of dolomite at different temperatures were obtained by calcining raw dolomite.Through characterizing the decomposition products of dolomite by using of TG-DTA,XRD,FTIR and SEM,the changes of product composition and activity during the decomposition process of the dolomite were studied,and the crystal structure transition of the dolomite during calcining process was investigated.The results show that the decomposition of dolomite can be divided into MgCO3 decomposition,small amount of CaCO3 decomposition and a great deal of CaCO3 decomposition stages under the calcination condition of 10℃/min.The decomposition of dolomite begins at about 800℃,and the decomposition products are MgO and CaCO3,the active content of MgO in decomposition products increases with the increasing of calcination temperature,and the active MgO content can reach 15.78%.In the stage of small amount of CaCO3 decomposition,the decomposition products are MgO,CaCO3 and a small amount of CaO,and the active contents of the decomposition products are about 20%-23.78%.After a great quantity of CaCO3 is decomposed,the active contents in the decomposition products increase sharply,and the active oxide content can be more than 50%,finally the dolomite is completely decomposed into CaO and MgO.

袁碧隆;段思雨;刘宝;曹大力

沈阳化工大学材料科学与工程学院,辽宁沈阳 110142||斯达半导体有限公司,浙江嘉兴 314000沈阳化工大学材料科学与工程学院,辽宁沈阳 110142沈阳化工大学材料科学与工程学院,辽宁沈阳 110142沈阳化工大学材料科学与工程学院,辽宁沈阳 110142

矿业与冶金

白云石热分解活性MgOCaCO3晶体结构

dolomitethermal decompositionactive MgOCaCO3crystal structure

《铸造》 2026 (1)

41-46,6

辽宁省国家级大学生创新创业训练计划项目(202510149070).

10.27014/j.cnki.zhuzao.2026.0007

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