功能化介孔材料的合成策略及其催化应用OA

Mesoporous materials are known as"star"functional materials due to their large specific surface area,regularly ordered pore structure,and continuously adjustable pore size,which demonstrate excellent performance in adsorption and separation,catalysis,and energy storage.Using some typical mesoporous materials,including mesoporous carbon,mesoporous silicon,mesoporous TiO2,and mesoporous materials with asymmetric structure as examples,various preparation methods were reviewed,including hard templating,microemulsion techniques,interfacial dynamic migration,evaporation-driven directional assembly,surface dynamics control,and emulsion-driven methods.Additionally,the applications of mesoporous materials in energy and environmental catalysis were examined,particularly in Fenton-like degradation of pollutants,(electro)photocatalytic CO2 reduction,degradation of volatile organic compounds(VOCs),purification of automobile exhaust,and Fischer-Tropsch synthesis.Finally,the future development and the prospects for advancement of mesoporous materials were discussed.