首页|期刊导航|常州大学学报(自然科学版)|含氟聚合物包覆方法对纳米级铝粉燃烧特性的影响

含氟聚合物包覆方法对纳米级铝粉燃烧特性的影响OA

Effect of fluoropolymer coating method on combustion characteristics of nano-aluminum powder

中文摘要英文摘要

采用含氟聚合物包覆铝粉可以显著提升其燃烧性能,然而含氟聚合物存在包覆不均匀的问题.本文采用蒸发重结晶法和溶剂-非溶剂法在纳米铝(nAl)颗粒表面包覆聚偏氟乙烯(PVDF),研究其点火燃烧性能.利用扫描电镜和X射线光电子能谱对其包覆结构和燃烧产物进行了表征.发现溶剂-非溶剂法包覆nAl的效果优于蒸发重结晶法,nAl表面有PVDF丝状纤维包覆.利用光学传感器和高速摄像装置检测不同样品在空气中的点火和燃烧性能,发现采用溶剂-非溶剂法包覆,在PVDF质量分数达到16%时,包覆的nAl样品燃烧效果较好,点火延迟时间明显缩短.该研究为后续含氟聚合物包覆改性Al粉的燃烧性能提升提供参考.

The use of fluoropolymer coating aluminum powder can significantly improve the combus-tion performance of aluminum powder.However,fluoropolymers have the problem of uneven coat-ing.In this paper,the evaporative recrystallization method and solvent/non-solvent method were used to coat the surface of nano-aluminum(nAl)particles with PVDF,and their ignition and combustion properties were studied.Scanning electron microscopy and X-ray photoelectron spectroscopy were used to characterize the enveloping structure and combustion products.It was found that the effect of solvent/non-solvent method of nAl coating was better than that of evaporation recrystallization meth-od,and the surface of nAl was coated with PVDF filamentous fibers.Optical sensors and high-speed cameras were used to detect the flame propagation and combustion performance of different samples in the air,and it was found that the solvent-non-solvent coating method had better combustion effect when the PVDF concentration was above 16%,and the ignition delay time was shortened.This study provides a reference for the subsequent improvement of the combustion performance of fluoropolymer-coated modified Al powder.

王佳欣;吴英健;韩志垒;朱宝忠;孙运兰

常州大学 石油与天然气工程学院,江苏 常州 213164常州大学 石油与天然气工程学院,江苏 常州 213164常州大学 石油与天然气工程学院,江苏 常州 213164常州大学 石油与天然气工程学院,江苏 常州 213164常州大学 石油与天然气工程学院,江苏 常州 213164

军事科技

AlPVDF包覆燃烧性能

AlPVDFcoatedcombustion performance

《常州大学学报(自然科学版)》 2026 (1)

81-92,12

国家自然科学基金资助项目(52176099).

10.3969/j.issn.2095-0411.2026.01.010

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