某冶炼厂金精矿生物氧化液中和除硬度试验探究OA
Experimental Study on Hardness Removal by Neutralization of Bio-oxidation Solution from Gold Concentrate in a Smelter
针对某冶炼厂金精矿生物氧化液处理中的中和与除硬度难题,通过"石灰石+石灰"二段中和联合CO2 软化工艺,系统研究药剂组合与工艺参数对中和除硬度效果的影响.结果表明:二段中和工艺较传统方法吨精矿节约石灰粉 450.6 kg,成本降低 194 元;优化石灰石粒度至 91.5 μm后药剂用量减少 20%,过滤时间稳定在 2.5 min.采用Ca(OH)2 调控pH至 12,反应时间为15 min,实现98%的Mg2+去除率,结合CO₂控制pH至 11.5,总硬度由 2800 mg/L降至 275 mg/L(优于GB/T 19923-2005),重金属含量达标且钠离子累积可控.该工艺构建了高效低成本的生物氧化液资源化利用方案,为冶炼废水减量化提供技术支撑.
Aiming at the problems of neutralization and hardness removal in the treatment of bio-oxidation solution of gold concentrate in a smelter,the"limestone+lime"two-stage neutralization combined with the CO2 softening process was adopted to systematically study the effects of reagent combinations and process parameters.The results show that:compared with the traditional method,the two-stage neutralization process saves 450.6 kg of lime powder per ton of concentrate,and the cost is reduced by 194 yuan per ton of concentrate;after optimizing the limestone particle size to 91.5 μm,the reagent consumption is reduced by 20%,and the filtration time is stably maintained at 2.5 minutes.By using Ca(OH)2 to regulate the pH to 12 and reacting for 15 minutes,the removal rate of Mg2+reaches 98%.By combining with controlling the pH to 11.5 with CO2,the total hardness is reduced from 2800 mg/L to 275 mg/L(better than the standard of GB/T 19923-2005),the content of heavy metals meets the standard,and the accumulation of sodium ions can be controlled.This process constructs an efficient and low-cost resource utilization scheme for the bio-oxidation solution,providing technical support for the reduction of smelting wastewater.
章佳豪;毋争辉;王梅君;谢洪珍;王亮;徐芳
低品位难处理黄金资源综合利用国家重点实验室,福建 厦门 361101||厦门紫金矿冶技术有限公司,福建 厦门 361101陇南紫金矿业有限公司,甘肃 陇南 742500低品位难处理黄金资源综合利用国家重点实验室,福建 厦门 361101||厦门紫金矿冶技术有限公司,福建 厦门 361101低品位难处理黄金资源综合利用国家重点实验室,福建 厦门 361101||厦门紫金矿冶技术有限公司,福建 厦门 361101低品位难处理黄金资源综合利用国家重点实验室,福建 厦门 361101||厦门紫金矿冶技术有限公司,福建 厦门 361101低品位难处理黄金资源综合利用国家重点实验室,福建 厦门 361101||厦门紫金矿冶技术有限公司,福建 厦门 361101
生物氧化液二段中和硬度控制CO2软化
bio-oxidation solutionbio-oxidation solutionhardness controlCO2 softening
《福建冶金》 2026 (1)
1-4,4
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