首页|期刊导航|陕西科技大学学报|甲基对明胶-丙烯酸水凝胶基超级电容器性能的影响

甲基对明胶-丙烯酸水凝胶基超级电容器性能的影响OA

Effect of methyl on the performance of gelatin-acrylic hydrogel based supercapacitors

中文摘要英文摘要

明胶基水凝胶超级电容器的制备不仅有利于明胶的高值化利用,还有利于超级电容器环保性能的提升,然而明胶基水凝胶的力学性能往往较弱,而通过增加相互作用提高其力学性能的方法往往导致明胶基水凝胶的含水量降低从而降低其离子导电率.本研究对比了两种甲基含量显著不同的丙烯酸共聚物-明胶水凝胶的力学性能、导电性、及其应用于超级电容器的性能.研究表明,高甲基含量有利于提高丙烯酸共聚物-明胶水凝胶的分子链密集区域的分子链间相互作用,在相同含水量时,可保证其分子链疏松区域保留富水离子通道,从而实现高力学强度和低含水量的情况下水凝胶较高的离子导电率.利用其制备的超级电容器也具有更高的比电容和更好的电容特性.该研究为设计高强韧明胶基超级电容器提供了一定理论参考.

The preparation of gelatin-based hydrogel supercapacitors not only facilitates the high-value utilization of gelatin but also contributes to the eco-friendly performance improve-ment of supercapacitors.However,the mechanical properties of gelatin-based hydrogels are usually weak,and the methods to improve their mechanical properties by increasing the mo-lecular interactions often lead to a decrease in the water content of gelatin-based hydrogels,thus reducing their ionic conductivity.In this study,the mechanical properties,conductivity,application performance in supercapacitors of two acrylic acid copolymer-gelatin hydrogels with significantly different methyl contents were compared.The results showed that high methyl content can enhance the intermolecular interactions in the chain dense regions of the hydrogel.At same water content,it can ensure the rich water ion channels in the chain loose regions,thus achieving a high mechanical strength and low water content while maintaining a high ionic conductivity of the hydrogels.The supercapacitors prepared from the hydrogel also have a higher specific capacitance and more ideal capacitive characteristics.This study pro-vides a certain reference for the design of high-strength and tough gelatin-based supercapaci-tors.

张慧洁;席双双;张文龙

陕西科技大学轻工科学与工程学院,陕西西安 710021陕西科技大学轻工科学与工程学院,陕西西安 710021陕西科技大学轻工科学与工程学院,陕西西安 710021

化学化工

明胶水凝胶超级电容器

gelatinhydrogelsupercapacitor

《陕西科技大学学报》 2026 (1)

15-23,9

国家自然科学基金项目(22002079)陕西省科技厅重点研发计划项目(2023-YBGY-485)中国国家留学基金项目(2024)

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