高导电柔性PDA/PPy加热棉织物的制备及性能研究OA
Preparation and Performance Study of Highly Conductive Flexible PDA/PPy Heated Cotton Fabrics
随着可穿戴设备的快速发展,柔性电加热织物因其广阔的应用前景而备受关注.然而,当前广泛使用的导电材料存在明显缺陷:金属材料柔性差、温度分布不均,而导电聚合物聚吡咯(PPy)则受限于其与织物基底间的弱界面结合力.为解决这一关键瓶颈,本研究受贻贝足丝蛋白启发,采用聚多巴胺(PDA)对棉织物改性,利用简单的原位聚合法在棉织物上构建了PDA-PPy导电层.实验结果表明,制备的柔性电加热织物具备较低的方阻(5.9 Ω)和优异的电热响应性能,仅需几十秒即可实现快速升温,并在5 V低电压下达到95.7℃的稳态温度,且具有良好的可调性.此外,该材料展现出卓越的加热-冷却循环稳定性,在20 次循环后电热性能衰减率仅为7.2%,同时在多种弯曲形变下电阻变化率极低.本研究为解决导电聚合物与基底的界面结合问题提供了有效方案,所开发的复合材料在智能可穿戴领域显示出巨大的应用潜力.
With the rapid development of wearable devices,flexible electrically-heated fabrics have attracted significant attention due to their broad application prospects.However,widely-used conductive materials have obvious defects such as poor flexibility and uneven temperature distribution of metal materials and weak interfacial adhesion to textile substrates of conductive polymer polypyrrole(PPy).To address this critical bottleneck,in-spired by mussel foot proteins,polydopamine(PDA)was employed to modify cotton fabrics,and a PDA-PPy conductive layer on the cotton fabrics was constructed by using a simple in situ polymerization method.The ex-perimental results demonstrated that the prepared flexible electrically-heated fabrics possessed a relatively low sheet resistance(5.9 Ω)and excellent electrothermal response performance with good tunability,rapidly heating within just tens of seconds and reaching a steady-state temperature of 95.7℃under a low voltage of 5 V.Moreo-ver,the material exhibited outstanding heating-cooling cycle stability with only a 7.2%decrease in electrother-mal performance after 20 cycles and very low resistance change rate under various bending deformations.The study provided an effective solution to the interfacial adhesion issue between conductive polymers and substrates,and the developed composite showed significant application potential in the field of smart wearables.
栗新娜;夏兆鹏;沈丽;王宁;宋志豪;崔利博;黄柯欣
天津工业大学纺织科学与工程学院,天津 300387天津工业大学纺织科学与工程学院,天津 300387||青海省产品质量检验检测院,青海 西宁 810000青海省产品质量检验检测院,青海 西宁 810000天津工业大学纺织科学与工程学院,天津 300387天津工业大学纺织科学与工程学院,天津 300387天津工业大学纺织科学与工程学院,天津 300387天津工业大学纺织科学与工程学院,天津 300387
轻工纺织
多巴胺吡咯柔性导电性耐用性
dopaminepyrroleflexibilityconductivitydurability
《纺织科学与工程学报》 2026 (1)
1-9,15,10
国家市场监督管理总局科技计划项目(2023MK122)
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