固碳轻质土制备方法与物理力学性能研究OA
Research on preparation method and physical-mechanical properties of carbon sequestration lightweight soil
为减少碳排放、探寻岩土工程的二氧化碳(CO2)利用技术,基于氧化镁(MgO)碳化固化原理,提出了一种固碳轻质土(carbon sequestration lightweight soil,C-LS)原理,该原理采用MgO和渣土替代水泥作为固化材料、CO2替代空气发泡,将MgO、粉质黏土、水和CO2泡沫按一定比例混合后形成密度<1 g/cm3的C-LS.通过无侧限抗压强度、扫描电镜和热重等宏微观试验,研究了不同MgO掺量、设计湿密度、水固比与碳化养护条件对C-LS的流值、凝结时间、干密度、强度、碳化产物及固碳能力的影响规律.结果表明:随MgO掺量和湿密度增加,C-LS流值和凝结时间减小,抗压强度提高,同时其固碳量提高.确定了C-LS的最优配比,在自然养护下,其 28 d强度可满足高速公路路堤填筑和其它填筑材料要求,在外部加速碳化条件下,C-LS强度可进一步提高.根据C-LS强度与碳化产物产量及固碳量的内在联系,研究揭示了C-LS强度形成微观机理.C-LS技术能大量消耗CO2和工程渣土,为岩土工程固碳利用提供了崭新的技术途径.
To reduce carbon emissions and explore carbon dioxide(CO2)utilization technologies in geotechnical engineering,this study proposes a novel method for preparing carbon sequestration lightweight soil(C-LS)based on the magnesium oxide(MgO)carbonation mechanism.A mixture of MgO and waste soil is used as a binder instead of cement and CO2 instead of air for foaming.By mixing MgO,silty clay,water and CO2 foam in specific proportions,C-LS with a density of less than 1 g/cm3 is formed.Through unconfined compressive strength tests,scanning electron microscopy(SEM)and thermogravimetric analysis(TGA),the effects of MgO proportions,designed wet densities,water-to-solid ratios and carbonation curing conditions on the fluidity,setting time,dry density,strength,carbonation products and carbon sequestration capacity of C-LS are studied.The results show that with the increase of MgO proportion and wet density,the fluidity and setting time of C-LS decrease,while the strength and carbon sequestration efficiency improve.The optimal mix proportion of C-LS is determined,ensuring that under ambient conditions,its 28-day strength meets the requirements for highway embankment filling and other backfill applications.Under accelerated carbonation conditions,the strength of C-LS can be further improved.Based on the intrinsic relationship between the strength of C-LS,the amount of carbonation product,and the carbon sequestration rate,the study reveals the strength formation mechanism of C-LS and proposes a microscopic model.The C-LS technology can significantly consume CO2 and engineering waste soil,providing a novel technical approach for CO2 sequestration in geotechnical engineering.
LIU Songyu;ZHANG Xiang;CAI Guanghua;YUAN Zhenyang;AN Jingfeng;CHEN Guangwei
Institute of Geotechnical Engineering,Southeast University,Nanjing 211189,China||Nanjing Modern Multimodal Transportation Laboratory,Nanjing 211100,ChinaInstitute of Geotechnical Engineering,Southeast University,Nanjing 211189,ChinaSchool of Civil Engineering,Nanjing Forestry University,Nanjing 210037,ChinaInstitute of Geotechnical Engineering,Southeast University,Nanjing 211189,China||Nanjing Modern Multimodal Transportation Laboratory,Nanjing 211100,ChinaJiangsu Provincial Transportation Engineering Construction Bureau,Nanjing 210004,ChinaJiangsu Provincial Transportation Engineering Construction Bureau,Nanjing 210004,China
建筑与水利
C-LSMgO二氧化碳泡沫制备方法物理力学特性
C-LSMgOCO2 foampreparation methodphysical and mechanical properties
《岩土工程学报》 2026 (1)
15-23,9
国家自然科学基金面上项目(42277146)江苏省研究生科研创新计划(KYCX23_0287)This study was supported by the National Natural Science Foundation of China(Grant No.42277146)and the Postgraduate Research&Practice Innovation Program of Jiangsu Province(Grant No.KYCX23_0287).
评论