镁渣基碳化养护加气混凝土的制备OA北大核心
Preparation of carbonation aerated concrete based on magnesium slag
针对建材行业碳排放较高的问题,提出基于碳化养护代替传统蒸压养护方式制备一种浇筑成型的镁渣基碳矿化加气混凝土(MCAC).将大量镁渣粉与少量水泥加水拌和,由水泥提供前期脱模强度,镁渣提供碳化养护后试样的强度,并利用铝粉发气降低干密度,设计制作干密度低于750 kg/m3的MCAC试样.通过控制水固比、碳化时间、预干燥处理时间等变量探究最佳的碳化养护方式,并对试样的微观结构进行表征.结果表明:制备时控制水固比为0.24最佳;12h标准养护后,碳化前试块的抗压强度基本为0,经过不同时间碳化养护后,MCAC抗压强度最高达到5.3 MPa;通过预干燥处理的方式来调控碳化前期试块含水率,确定含水量为16%为最佳;此外,MCAC通过碳化养护生成了以大量方解石和少量文石为主要晶型的碳酸钙,填充了孔隙,优化了孔径分布,增强了试样的力学性能.该研究为制备一种新型绿色、可持续发展的加气混凝土提供思路,并达到了固化二氧化碳的目的.
Magnesium slag is an industrial by-product of magnesium production,which exhibits high carbonation activity due to the presence of large amount of dicalcium silicate in its composition.Here,a MS-based carbonated aerated concrete(MCAC)is reported.The mixture is mainly composed of MS powder,supplemented with a small amount of Portland cement with high hydration activity to provide demolding strength.The density of MCAC(750 kg/m3)is regulated by aluminum powder,and the effect of different carbonation systems on the mechanical prop-erties and void structure is studied.By controlling the water to solid ratio,carbonization time and pre-drying treat-ment time,the best carbonization system is explored.The results reveal that the water to solid ratio of 0.24 is de-termined to be the best;there is almost zero of the compressive strength of MCAC after 12 h standard pre-curing(before carbonation).After carbonation for 24 h at 0.1 MPa,the compressive strength of MCAC reaches 5.3 MPa.The moisture before carbonation of 16%is considered as the optimum value,which can be controlled by pre-dying treatment.In addition,a large amount of calcium carbonate with calcite and a small amount of aragonite as the main crystal is generated after carbonation,which gradually deposits on the void inner surface along with the carbonation.This study provides a new insight into the preparation of a new type of green and sustainable aer-ated concrete,accompanied by the achievement of CO2 solidification.
邓思敏;刘志超;雷鸣
武汉理工大学材料科学与工程学院,武汉 430070武汉理工大学材料科学与工程学院,武汉 430070||武汉理工大学硅酸盐建筑材料国家重点实验室,武汉 430070武汉理工大学材料科学与工程学院,武汉 430070
建筑与水利
镁渣碳化加气混凝土抗压强度微观结构
magnesium slagcarbonizationaerated concretecompressive strengthmicrostructure
《桂林理工大学学报》 2025 (2)
221-228,8
国家自然科学基金项目(U20012275192520552130208)
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