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河南绿色密玉的宝石学特征和颜色成因OA北大核心CSTPCD

Gemological characteristies and color genesis of green Miyu jade from Henan,China

中文摘要英文摘要

河南密玉是我国重要的玉石品种,属于显晶质石英岩.前人对于河南省新密市的密玉玉石矿床进行了系统的地质学研究,但其宝石学特征和颜色成因仍存在争议.文章综合了前人的研究成果,对河南密玉中的绿色系列样品进行了常规宝石学测试、红外光谱测试、紫外-可见光光谱测试、拉曼测试以及电子探针测试研究.结果表明,密玉为结晶度较好的石英岩,主要矿物成分为α-石英,次要矿物有白云母、赤铁矿、石墨、金红石、电气石等;具有花岗变晶结构和显微细粒变晶结构;紫外-可见光光谱中可见明显的Cr3+特征吸收峰;密玉的绿色与含铬白云母有关,而含铬白云母的绿色则是由于其所含的微量元素Cr、V、Ni等致色元素引起的,绿色越深,Cr、Ni、V含量越高;随着Fe3+含量增加,样品的黄色调越明显.

Henan Miyu jade is an important variety of jade in China,which belongs to the phanerocrystalline quar-tzite.A systematic geological study of the Miyu jade deposit in Xinmi City,Henan Province,has been carried out,but its gemmological characteristics and color genesis remain controversial.This paper synthesizes the research re-sults of the previous researchers,and obtains the gemological characteristics,spectroscopic research characteristics and chemical composition characteristics of the green series of Henan Miyu jade samples by routine gemological tes-ting,FTIR spectroscopy,UV-Ⅵs spectroscopy,Raman testing and electron microprobe testing.The results show that Miyu jade is a quartzite with good crystallinity.The main mineral component is α-quartz,and minor minerals include muscovite,hematite,carbonaceous minerals,rutile,tourmaline,etc.It has a granular metamorphic struc-ture and a microscopic fine-grained metamorphic structure.Significant characteristic absorption peaks of Cr3+were seen in the UV-visible spectrum.The green color of Miyu jade is related to chromium-containing white mica,and the green color of chromium-containing white mica is caused by the trace elements it contains,such as Cr,V,Ni and other color-causing elements.The darker the green color,the higher the content of Cr,Ni and V.With the increase of Fe3+content,the yellow tone of the sample is more obvious.

李汶娟;余晓艳;白峰

中国地质大学(北京)珠宝学院,北京 100083

地质学

绿色密玉;石英质玉;宝石学特征;颜色成因;河南

green Miyu jade;quartzartzite jade;gemological characteristics;color genesis;Henan

《岩石矿物学杂志》 2024 (003)

697-708 / 12

10.20086/j.cnki.yskw.2024.0317

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