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MAX相陶瓷增强金属基复合材料:制备、性能与仿生设计OA北大核心CSTPCD

Metal Matrix Composites Reinforced by MAX Phase Ceramics:Fabrication,Properties and Bioinspired Designs

中文摘要英文摘要

由于原子间存在共价键、金属键与离子键的混合键合状态,MAX 相陶瓷兼具金属和陶瓷材料的性能特点,并且常与金属之间表现出良好的润湿性,有助于形成强界面结合,独特的层状原子结构使MAX相陶瓷表现出良好的断裂韧性、阻尼与自润滑性能.因此,作为金属基复合材料的增强相,MAX相陶瓷具有显著优势,本文着重介绍相关研究进展.目前,MAX 相陶瓷增强金属基复合材料主要通过搅拌铸造、粉末冶金和熔体浸渗等途径制备,得到的复合材料表现出优于金属基体的强度、硬度与模量,同时还具备良好的耐磨、导电、抗电弧侵蚀等性能.此外,借助真空抽滤、冰模板等工艺可实现超细片状MAX相陶瓷粉体的择优定向排列,然后利用金属熔体浸渗多孔陶瓷骨架,可获得具有类贝壳结构的 MAX 相陶瓷增强金属基仿生复合材料,进一步提升材料的强韧性能.MAX 相陶瓷增强金属基复合材料在承载、电接触等应用领域具有显著优势和广阔前景.

MAX phase ceramics,with their mixed covalent-metallic-ionic atomic bonds,can uniquely combine the advantages of both metals and ceramics,offering a series of distinctive characteristics.The particular layered atomic structure further endows them with decent fracture toughness,good damping capacity,and self-lubricating property.As such,MAX phase ceramics are more appealing to serve as reinforcements for metal matrix composites(MMCs)than conventional ceramic materials.Here,we foused on the development.To date,fabrication of MMCs reinforced by MAX phase ceramics still involves the use of stir casting,powder metallurgy,and melt infiltration techniques.The obtained composites made by different methods may display distinct differences in their structural characteristics,show notable enhancement in strength,hardness,and stiffness as compared to their metal matrices,and exhibit good wear resistance,high electrical conductivity and remarkable arc erosion resistance.Moreover,ultrafine MAX phase platelets can be preferentially oriented and aligned,e.g.,by using vacuum filtration or ice templating techniques.By infiltrating metal melt into partially sintered porous ceramic scaffolds,bioinspired composites with nacre-like architectures can be obtained,thereby affording further improvement in strength and fracture toughness.Sufficient combinations of mechanical and functional properties enable the MMCs reinforced by MAX phase ceramics promising for a variety of applications,such as load-bearing structures,electrical contact materials.These composites can offer enhanced strength,stiffness,and wear resistance,making them ideal candidates for these applications.

刘艳艳;谢曦;刘增乾;张哲峰

中国科学院 金属研究所, 沈阳 110016||中国科学技术大学 材料科学与工程学院, 沈阳 110016中国科学院 金属研究所, 沈阳 110016

MAX相陶瓷;金属基复合材料;仿生设计;力学性能;熔体浸渗;专题评述

MAX phase ceramics;metal matrix composite;bioinspired design;mechanical property;melt infiltration;perspective

《无机材料学报》 2024 (002)

类贝壳结构陶瓷—树脂仿生复合材料的疲劳损伤机制与性能优化

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国家重点研发计划(2020YFA0710404);国家自然科学基金(52173269,52321001)National Key R&D Program of China(2020YFA0710404);National Natural Science Foundation of China(52173269,52321001)

10.15541/jim20230425

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